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• W3163156575 startingPage "383" @default.
• W3163156575 abstract "Methanol-to-olefin conversion is one of the most successful approaches to producing light olefins. It has been proved that SAPO-34 is the best catalyst for this process. This molecular-sieve is characterized by high thermal stability, moderate acid sites, and shape selectivity. In this report, SAPO-34 was synthesized using the seed-assisted method. Effects of OSDA and seed on crystallinity and particle size were investigated using Central Composite Design. Samples were characterized by XRD, FE-SEM, FTIR, BET, EDX, and TPD. Results showed that the samples had excellent physicochemical properties. The design of Experiments could predict the results accurately (R2 > 0.9). It was demonstrated that template was the key factor in the seed-assisted synthesis of SAPO-34. Template consumption was reduced by 50%, and it was proved that the synthesis time could be effectively decreased to 3 h due to rapid nucleation. Samples exhibited 100% methanol conversion and up to 90% selectivity toward ethylene and propylene." @default.
• W3163156575 created "2021-05-24" @default.
• W3163156575 creator A5002527818 @default.
• W3163156575 creator A5019281940 @default.
• W3163156575 creator A5075319029 @default.
• W3163156575 date "2021-09-01" @default.
• W3163156575 modified "2023-09-25" @default.
• W3163156575 title "Seeding-induced nano-sized SAPO-34 synthesis with superior MTO performance: Energy-efficient approach with highly reduced OSDA consumption" @default.
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• W3163156575 doi "https://doi.org/10.1016/j.powtec.2021.05.042" @default.
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