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• W3163302495 endingPage "109540" @default.
• W3163302495 startingPage "109540" @default.
• W3163302495 abstract "The ion transport mechanisms in passive films pre-formed on CoCrFeMnNi high entropy alloy surfaces in acid solution were studied in-situ by time-of-flight secondary ion mass spectrometry upon oxidation in 18O2 gas. The bilayer structure of the passive film, with outer Fe, Co-rich and inner Cr, Mn-rich layers, is thermally stable, but with reduction of Fe and Co oxides and formation of Mn oxide in the outer layer above 150 °C. At 170 °C, the transport mechanism is mainly outward cation diffusion with slower inward oxygen diffusion. The re-oxidation growth rate follows a parabolic law and the value of parabolic constant was determined." @default.
• W3163302495 created "2021-05-24" @default.
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• W3163302495 date "2021-08-01" @default.
• W3163302495 modified "2023-10-13" @default.
• W3163302495 title "Insight on passivity of high entropy alloys: Thermal stability and ion transport mechanisms in the passive oxide film on CoCrFeMnNi surfaces" @default.
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• W3163302495 doi "https://doi.org/10.1016/j.corsci.2021.109540" @default.
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