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• W3163492595 startingPage "4463" @default.
• W3163492595 abstract "We describe, for the first time, a highly regioselective hydrosilylation of propargylic amines. The reaction utilizes a PtCl2/XantPhos catalyst system to deliver hydrosilanes across the alkyne to afford multifunctional allylic amines in high yields. The reaction is tolerant to a wide variety of functional groups and provides high value intermediates with two distinct functional handles. The synthetic applicability of the reaction has been shown through the synthesis of diverse ambiphilic aziridines." @default.
• W3163492595 created "2021-05-24" @default.
• W3163492595 creator A5031130037 @default.
• W3163492595 creator A5063358510 @default.
• W3163492595 date "2021-05-21" @default.
• W3163492595 modified "2023-10-02" @default.
• W3163492595 title "Regioselective Synthesis of Multifunctional Allylic Amines; Access to Ambiphilic Aziridine Scaffolds" @default.
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• W3163492595 doi "https://doi.org/10.1021/acs.orglett.1c01398" @default.
• W3163492595 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34018758" @default.
• W3163492595 hasPublicationYear "2021" @default.
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