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- W3163993452 abstract "Ammonia is a promising hydrogen carrier due to its high volumetric energy density and ease of liquefication under mild conditions, thus circumventing the safety and transportation issues of hydrogen. To couple the utilization of ammonia with renewable powers, it is essential to develop stable and efficient catalysts for ammonia synthesis and decomposition under mild conditions. New strategies in catalyst design need to be devised to address hydrogen poisoning, scaling limitations, and slow kinetics issues in renewable N-cycle catalysis under mild conditions. N-cycle catalysis featuring the recycling of nitrogen with hydrogen in a chemical process could exert a profound impact on human society for the eventual sustainable production of foods, chemicals, and fuels. The challenges for materials required to perform efficient catalysis to activate N2 and renewable H2 to NH3 and for the reversible reaction to facilitate the storage and transport of renewable energies, in addition to coupling with fuel cells, are of paramount importance. In this review, we highlight and discuss the importance of the diverse position of NH3 as a fuel, fertilizer, and chemical vector. This review also provides an overview of the recent developments in ammonia synthesis and the decomposition of some promising materials and their prospects in these new processes. N-cycle catalysis featuring the recycling of nitrogen with hydrogen in a chemical process could exert a profound impact on human society for the eventual sustainable production of foods, chemicals, and fuels. The challenges for materials required to perform efficient catalysis to activate N2 and renewable H2 to NH3 and for the reversible reaction to facilitate the storage and transport of renewable energies, in addition to coupling with fuel cells, are of paramount importance. In this review, we highlight and discuss the importance of the diverse position of NH3 as a fuel, fertilizer, and chemical vector. This review also provides an overview of the recent developments in ammonia synthesis and the decomposition of some promising materials and their prospects in these new processes. a synergistic orbital interaction between a transition metal and a pi-conjugated ligand. a kind of gas-surface adsorption that leads to the dissociation of a diatomic molecule. a class of ionic compounds where electrons serve as anions. the ‘green alternative’ to the traditional HB process where brown hydrogen generated from steam reforming is replaced by green hydrogen generated from electrolysis of water from renewables. the highly energy-intensive industrial production of ammonia that occurs at 500°C and 250 bar, producing a tremendous amount of CO2 and consuming more than 1% of global energy every year. a phenomenon where metal active sites on a catalyst are blocked by adsorbed H atoms. the slowest step in a chemical reaction that determines the overall rate of the reaction process. a type of plot with an inverted V-shape describing the ‘ideal’ adsorption interaction between a catalyst and a substrate." @default.
- W3163993452 created "2021-06-07" @default.
- W3163993452 creator A5058130044 @default.
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- W3163993452 date "2021-08-01" @default.
- W3163993452 modified "2023-10-02" @default.
- W3163993452 title "Renewable N-cycle catalysis" @default.
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- W3163993452 doi "https://doi.org/10.1016/j.trechm.2021.04.010" @default.
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