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• W3164156960 endingPage "633" @default.
• W3164156960 startingPage "633" @default.
• W3164156960 abstract "Herein, we present the photovoltaic properties of an indium phthalocyanine chloride (InClPc)-based flexible planar heterojunction device, introducing the tetrathiafulvene derivative 4,4′-Dimethyl-5,5′-diphenyltetrathiafulvalene (DMDP-TTF) as the electron donor layer. UV-vis spectroscopy is widely used to characterize the electronic behavior of the InClPc/DMDP-TTF active layer. The interactions between the DMDP-TTF and phthalocyanine are predominantly intermolecular and the result of the aggregation of InClPc. Tauc bands were obtained at 1.41 and 2.8 eV; these energy peaks can result in a charge transfer ascribed to the transition from the DMDP-TTF to π-orbitals that are associated with the phthalocyanine ring or even with the same indium metal center. Conductive carbon (CC) was used for the cathode. Finally, an indium tin oxide (ITO)/InClPc/DMDP-TTF/CC device was fabricated by high-vacuum thermal evaporation onto a flexible substrate and the photovoltaic properties were evaluated. A diode type I-V curve behavior was observed with a photovoltaic response under illumination. A generated photocurrent of 2.25 × 10−2 A/cm2 was measured. A conductivity reduction with the incident photon energy from 1.61 × 10−7 S/cm to 1.43 × 10−7 S/cm is observed. The diode resistance presents two different behaviors with the applied voltage. A VTFL of 5.39 V, trap concentration of 7.74 × 1016 cm−3, and carrier mobility values of ~10−6 cm2/V s were calculated, showing improved characteristics via the innovative implementation of an alternative TTF-derivative, indicating that the DMDP-TTF has a strong interaction at the junction where free available states are increased, thus inducing higher mobilities due to the large number of π-orbitals, which indicates the feasibility of its use in solar cells technology." @default.
• W3164156960 created "2021-06-07" @default.
• W3164156960 creator A5005797071 @default.
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• W3164156960 date "2021-05-29" @default.
• W3164156960 modified "2023-09-30" @default.
• W3164156960 title "Innovative Implementation of an Alternative Tetrathiafulvene Derivative for Flexible Indium Phthalocyanine Chloride-Based Solar Cells" @default.
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• W3164156960 doi "https://doi.org/10.3390/mi12060633" @default.
• W3164156960 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/8229926" @default.
• W3164156960 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34072414" @default.
• W3164156960 hasPublicationYear "2021" @default.
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