Matches in SemOpenAlex for { <https://semopenalex.org/work/W3164253588> ?p ?o ?g. }
- W3164253588 endingPage "16941" @default.
- W3164253588 startingPage "16937" @default.
- W3164253588 abstract "Abstract Non‐noble transition metal complexes have attracted growing interest as efficient electrocatalysts for oxygen reduction reaction (ORR) while their activities still lack rational and effective regulation. Herein, we propose a d–π conjugation strategy for rough and fine tuning of ORR activity of TM‐BTA (TM=Mn/Fe/Co/Ni/Cu, BTA=1,2,4,5‐benzenetetramine) coordination polymers. By first‐principle calculations, we elucidate that the strong d–π conjugation elevates the d xz /d yz orbitals of TM centers to enhance intermediate adsorption and strengthens the electronic modulation effect from substitute groups on ligands. Based on this strategy, Co‐TABQ (tetramino benzoquinone) is found to approach the top of ORR activity volcano. The synthesized Co‐TABQ with atomically distributed Co on carbon nanotubes exhibits a half‐wave potential of 0.85 V and a specific current of 127 mA mg metal −1 at 0.8 V, outperforming the benchmark Pt/C. The high activity, low peroxide yield, and considerable durability of Co‐BTA and Co‐TABQ promise their application in oxygen electrocatalysis. This study provides mechanistic insight into the rational design of transition metal complex catalysts." @default.
- W3164253588 created "2021-06-07" @default.
- W3164253588 creator A5019957757 @default.
- W3164253588 creator A5037738045 @default.
- W3164253588 creator A5038767359 @default.
- W3164253588 creator A5063230535 @default.
- W3164253588 creator A5074474376 @default.
- W3164253588 creator A5075550454 @default.
- W3164253588 creator A5081251401 @default.
- W3164253588 creator A5082857859 @default.
- W3164253588 creator A5086427768 @default.
- W3164253588 creator A5087498131 @default.
- W3164253588 creator A5089669072 @default.
- W3164253588 date "2021-06-26" @default.
- W3164253588 modified "2023-10-16" @default.
- W3164253588 title "Regulating Electrocatalytic Oxygen Reduction Activity of a Metal Coordination Polymer via d–π Conjugation" @default.
- W3164253588 cites W2043203678 @default.
- W3164253588 cites W2083788575 @default.
- W3164253588 cites W2323236118 @default.
- W3164253588 cites W2411101553 @default.
- W3164253588 cites W2524524179 @default.
- W3164253588 cites W2527110365 @default.
- W3164253588 cites W2611902734 @default.
- W3164253588 cites W2618288086 @default.
- W3164253588 cites W2736954604 @default.
- W3164253588 cites W2774418387 @default.
- W3164253588 cites W2776793436 @default.
- W3164253588 cites W2792063676 @default.
- W3164253588 cites W2953517522 @default.
- W3164253588 cites W2966571047 @default.
- W3164253588 cites W2982071821 @default.
- W3164253588 cites W2984167316 @default.
- W3164253588 cites W3000584101 @default.
- W3164253588 cites W3008165181 @default.
- W3164253588 cites W3014745357 @default.
- W3164253588 cites W3034948166 @default.
- W3164253588 cites W3039568674 @default.
- W3164253588 cites W3044206712 @default.
- W3164253588 cites W3056746006 @default.
- W3164253588 cites W3066041726 @default.
- W3164253588 cites W4205425855 @default.
- W3164253588 cites W4230283721 @default.
- W3164253588 cites W4231999573 @default.
- W3164253588 cites W4238876709 @default.
- W3164253588 cites W4361866491 @default.
- W3164253588 doi "https://doi.org/10.1002/anie.202104494" @default.
- W3164253588 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34051024" @default.
- W3164253588 hasPublicationYear "2021" @default.
- W3164253588 type Work @default.
- W3164253588 sameAs 3164253588 @default.
- W3164253588 citedByCount "50" @default.
- W3164253588 countsByYear W31642535882022 @default.
- W3164253588 countsByYear W31642535882023 @default.
- W3164253588 crossrefType "journal-article" @default.
- W3164253588 hasAuthorship W3164253588A5019957757 @default.
- W3164253588 hasAuthorship W3164253588A5037738045 @default.
- W3164253588 hasAuthorship W3164253588A5038767359 @default.
- W3164253588 hasAuthorship W3164253588A5063230535 @default.
- W3164253588 hasAuthorship W3164253588A5074474376 @default.
- W3164253588 hasAuthorship W3164253588A5075550454 @default.
- W3164253588 hasAuthorship W3164253588A5081251401 @default.
- W3164253588 hasAuthorship W3164253588A5082857859 @default.
- W3164253588 hasAuthorship W3164253588A5086427768 @default.
- W3164253588 hasAuthorship W3164253588A5087498131 @default.
- W3164253588 hasAuthorship W3164253588A5089669072 @default.
- W3164253588 hasConcept C106773901 @default.
- W3164253588 hasConcept C147789679 @default.
- W3164253588 hasConcept C161790260 @default.
- W3164253588 hasConcept C171250308 @default.
- W3164253588 hasConcept C17525397 @default.
- W3164253588 hasConcept C178790620 @default.
- W3164253588 hasConcept C185592680 @default.
- W3164253588 hasConcept C192562407 @default.
- W3164253588 hasConcept C21951064 @default.
- W3164253588 hasConcept C2992754303 @default.
- W3164253588 hasConcept C33989665 @default.
- W3164253588 hasConcept C52859227 @default.
- W3164253588 hasConcept C53105671 @default.
- W3164253588 hasConcept C540031477 @default.
- W3164253588 hasConcept C544153396 @default.
- W3164253588 hasConceptScore W3164253588C106773901 @default.
- W3164253588 hasConceptScore W3164253588C147789679 @default.
- W3164253588 hasConceptScore W3164253588C161790260 @default.
- W3164253588 hasConceptScore W3164253588C171250308 @default.
- W3164253588 hasConceptScore W3164253588C17525397 @default.
- W3164253588 hasConceptScore W3164253588C178790620 @default.
- W3164253588 hasConceptScore W3164253588C185592680 @default.
- W3164253588 hasConceptScore W3164253588C192562407 @default.
- W3164253588 hasConceptScore W3164253588C21951064 @default.
- W3164253588 hasConceptScore W3164253588C2992754303 @default.
- W3164253588 hasConceptScore W3164253588C33989665 @default.
- W3164253588 hasConceptScore W3164253588C52859227 @default.
- W3164253588 hasConceptScore W3164253588C53105671 @default.
- W3164253588 hasConceptScore W3164253588C540031477 @default.
- W3164253588 hasConceptScore W3164253588C544153396 @default.
- W3164253588 hasFunder F4320321001 @default.
- W3164253588 hasFunder F4320321540 @default.
- W3164253588 hasIssue "31" @default.