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- W3164865345 abstract "A helical metal-organic framework was prepared by using a conformationally rigid tetratopic benzoic acid ligand with binding units pointing toward each other (concave ligand). To avoid the obvious intramolecular interactions between binding units, matching spacing groups were applied to introduce atropic repulsion, thereby allowing the formation of extended frameworks for the first time. With this new ligand design, a helical-shaped MOF with significantly improved air and moisture stability was successfully prepared, thus providing a new strategy for ligand design toward porous material constructions." @default.
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- W3164865345 date "2021-06-22" @default.
- W3164865345 modified "2023-10-18" @default.
- W3164865345 title "Construction of Stable Helical Metal‐Organic Frameworks with a Conformationally Rigid “Concave Ligand”" @default.
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- W3164865345 doi "https://doi.org/10.1002/chem.202101173" @default.
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