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- W3165366958 abstract "Abstract Low‐molecular‐mass bio‐polyesters, such as lactic acid oligomers, constitute a growing category of plasticizers for poly (lactic acid), since they show good compatibility and are respectful of the environment. This study focuses on the glass transition of a series of oligomers with different molecular weights, with the aim of investigating how their associated dynamics occur. Dielectric and calorimetric results are combined to study the molecular mobility in a large temperature range. In comparison with poly (lactic acid), the oligomers exhibit a lower fragility index and smaller cooperative rearranging regions. Among oligomers, the fragility is clearly dependent on the molecular weight, whereas the variations of the cooperativity are subtler." @default.
- W3165366958 created "2021-06-07" @default.
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- W3165366958 date "2021-05-20" @default.
- W3165366958 modified "2023-10-18" @default.
- W3165366958 title "Fragility of short‐chain poly(lactic acid)s derivatives by combining dielectric spectroscopy and fast scanning calorimetry" @default.
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- W3165366958 doi "https://doi.org/10.1002/pol.20210129" @default.
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