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• W3166164311 startingPage "20817" @default.
• W3166164311 abstract "We report a novel example of electro-mediated photoredox catalysis (e-PRC) in the reductive cleavage of C(sp3 )-O bonds of phosphinated alcohols to alkyl carbanions. As well as deoxygenations, olefinations are reported which are E-selective and can be made Z-selective in a tandem reduction/photosensitization process where both steps are photoelectrochemically promoted. Spectroscopy, computation, and catalyst structural variations reveal that our new naphthalene monoimide-type catalyst allows for an intimate dispersive precomplexation of its radical anion form with the phosphinate substrate, facilitating a reactivity-determining C(sp3 )-O cleavage. Surprisingly and in contrast to previously reported photoexcited radical anion chemistries, our conditions tolerate aryl chlorides/bromides and do not give rise to Birch-type reductions." @default.
• W3166164311 created "2021-06-22" @default.
• W3166164311 creator A5005258392 @default.
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• W3166164311 creator A5067475475 @default.
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• W3166164311 creator A5086585022 @default.
• W3166164311 date "2021-08-16" @default.
• W3166164311 modified "2023-10-07" @default.
• W3166164311 title "Electro‐mediated PhotoRedox Catalysis for Selective C(sp³)–O Cleavages of Phosphinated Alcohols to Carbanions" @default.
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