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- W3166870596 abstract "The electrochemical oxidation of 3',4'-didodecyl-2,2':5',2''-terthiophene (3'4'-DDTT) at applied potential values lower than 0.8 V vs Ag/Ag+ leads to the formation of an anodic deposit that is prevalently constituted by the products of monomer coupling at positions 5 and 5''. Upon electrochemical cycling poly-3'4'-DDTT manifests three phenomena: the cathodic shift of the main peak of poly-3'4'-DDTT oxidation, the bathochromic shift of 60 nm for the main UV–vis absorption peak, and the IR spectral evolution consisting of the progressive increase of the signals of 2,5-substituted thiophenes at expense of the signals from 2-substituted thiophenes. The observed behavior was interpreted in terms of the presence of reactive oligomers trapped in pristine as-deposited poly-3'4'-DDTT, with the oligomers undergoing further coupling in the polymeric phase upon electrochemical cycling. This combination of findings led us to conclude that poly-3'4'-DDTT manifests solid-state polymerization. After voltammogram stabilization poly-3'4'-DDTT was electrochemically stressed. The system showed a reversible electrochemical behavior up to 0.9 V vs Ag/Ag+. A depiction of the evolution of the electronic bands in poly-3'4'-DDTT when passing from the pristine state to the electrochemically cycled state has been proposed, taking into account the combination of electrochemical and optical data." @default.
- W3166870596 created "2021-06-22" @default.
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- W3166870596 date "2021-06-01" @default.
- W3166870596 modified "2023-09-27" @default.
- W3166870596 title "Evidence of Solid-State Polymerization in Regioregular Poly-3′,4′-Didodecyl-2,2′:5′,2′′-Terthiophene During Electrochemical Cycling" @default.
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- W3166870596 doi "https://doi.org/10.1149/1945-7111/ac0b5c" @default.
- W3166870596 hasPublicationYear "2021" @default.
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