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- W3167279826 abstract "Abstract A curved stereogenic [6]paraphenylene ([6]PP), anchoring a chiral binaphthyl scaffold at 7,7’‐positions, was prepared and investigated for its properties as a solid‐state circularly polarized luminescence (CPL) dye. X‐ray analysis revealed a helically twisted structure of PP units induced by axial chirality of binaphthyl framework. The curved [6]PP exhibits fluorescence in powder and polymethyl methacrylate (PMMA) film as well as solution. A significant increase in quantum yield was observed for a non‐fluid PMMA film owing the suppression of the molecular motion. The g CPL values of the dye in solution and as PMMA film were almost the same (4.3–4.4×10 −3 ) and lager than that in powder. TD‐DFT calculations in the excited state suggest that the exciton can be delocalized into a twisted PP unit to produce a larger magnetic transition dipole moment." @default.
- W3167279826 created "2021-06-22" @default.
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- W3167279826 date "2020-11-23" @default.
- W3167279826 modified "2023-10-14" @default.
- W3167279826 title "Circularly Polarized Luminescence of a Stereogenic Curved Paraphenylene Anchoring a Chiral Binaphthyl in Solution and Solid State" @default.
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- W3167279826 doi "https://doi.org/10.1002/chem.202004283" @default.
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