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- W3167350985 abstract "Abstract Chiral tertiary boronic esters are important precursors to bioactive compounds and versatile synthetic intermediates to molecules containing quaternary stereocenters. The development of conjugate boryl addition to α,β-unsaturated amide has been hampered by the intrinsic low electrophilicity of the amide group. Here we show the catalytic asymmetric synthesis of enantioenriched tertiary boronic esters through hydroboration of β,β-disubstituted α,β-unsaturated amides. The Rh-catalyzed hydroboration occurs with previously unattainable selectivity to provide tertiary boronic esters in high enantioselectivity. This strategy opens a door for the hydroboration of inert Michael acceptors with high stereocontrol and may provide future applications in the synthesis of biologically active molecules." @default.
- W3167350985 created "2021-06-22" @default.
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- W3167350985 date "2021-06-18" @default.
- W3167350985 modified "2023-10-11" @default.
- W3167350985 title "Enantioselective synthesis of tertiary boronic esters through catalytic asymmetric reversed hydroboration" @default.
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- W3167350985 doi "https://doi.org/10.1038/s41467-021-24012-z" @default.
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