Matches in SemOpenAlex for { <https://semopenalex.org/work/W3167996871> ?p ?o ?g. }
Showing items 1 to 90 of
90
with 100 items per page.
- W3167996871 abstract "Abstract Thermally stable photoswitches that are driven with low-energy light are rare, yet crucial for extending the applicability of photoresponsive molecules and materials towards, e.g., living systems. Combined ortho-fluorination and -amination couples high visible-light absorptivity of o-aminoazobenzenes with the extraordinary bistability of o-fluoroazobenzenes. Herein, we report a library of easily accessible o-aminofluoroazobenzenes and establish structure–property relationships regarding spectral qualities, visible light isomerization efficiency and thermal stability of the cis-isomer with respect to the degree of o-substitution and choice of amino substituent. We rationalize the experimental results with quantum chemical calculations, revealing the nature of low-lying excited states and providing insight into thermal isomerization. The synthesized azobenzenes absorb at up to 600 nm and their thermal cis-lifetimes range from milliseconds to months. The most unique example can be driven from trans to cis with any wavelength from UV up to 595 nm, while still exhibiting a thermal cis-lifetime of 81 days." @default.
- W3167996871 created "2021-06-22" @default.
- W3167996871 creator A5016940345 @default.
- W3167996871 creator A5029202496 @default.
- W3167996871 creator A5036131204 @default.
- W3167996871 creator A5061906414 @default.
- W3167996871 creator A5079384361 @default.
- W3167996871 creator A5080133788 @default.
- W3167996871 creator A5091117969 @default.
- W3167996871 date "2021-06-14" @default.
- W3167996871 modified "2023-10-13" @default.
- W3167996871 title "Towards low-energy-light-driven bistable photoswitches: ortho-fluoroaminoazobenzenes" @default.
- W3167996871 doi "https://doi.org/10.21203/rs.3.rs-608595/v1" @default.
- W3167996871 hasPublicationYear "2021" @default.
- W3167996871 type Work @default.
- W3167996871 sameAs 3167996871 @default.
- W3167996871 citedByCount "1" @default.
- W3167996871 countsByYear W31679968712021 @default.
- W3167996871 crossrefType "posted-content" @default.
- W3167996871 hasAuthorship W3167996871A5016940345 @default.
- W3167996871 hasAuthorship W3167996871A5029202496 @default.
- W3167996871 hasAuthorship W3167996871A5036131204 @default.
- W3167996871 hasAuthorship W3167996871A5061906414 @default.
- W3167996871 hasAuthorship W3167996871A5079384361 @default.
- W3167996871 hasAuthorship W3167996871A5080133788 @default.
- W3167996871 hasAuthorship W3167996871A5091117969 @default.
- W3167996871 hasBestOaLocation W31679968711 @default.
- W3167996871 hasConcept C121332964 @default.
- W3167996871 hasConcept C126661725 @default.
- W3167996871 hasConcept C159467904 @default.
- W3167996871 hasConcept C161790260 @default.
- W3167996871 hasConcept C178790620 @default.
- W3167996871 hasConcept C181500209 @default.
- W3167996871 hasConcept C184779094 @default.
- W3167996871 hasConcept C185592680 @default.
- W3167996871 hasConcept C192562407 @default.
- W3167996871 hasConcept C198503264 @default.
- W3167996871 hasConcept C204530211 @default.
- W3167996871 hasConcept C2778689049 @default.
- W3167996871 hasConcept C32909587 @default.
- W3167996871 hasConcept C49040817 @default.
- W3167996871 hasConcept C59061564 @default.
- W3167996871 hasConcept C62520636 @default.
- W3167996871 hasConcept C6260449 @default.
- W3167996871 hasConcept C71240020 @default.
- W3167996871 hasConcept C75473681 @default.
- W3167996871 hasConcept C84114770 @default.
- W3167996871 hasConcept C97292510 @default.
- W3167996871 hasConcept C97355855 @default.
- W3167996871 hasConceptScore W3167996871C121332964 @default.
- W3167996871 hasConceptScore W3167996871C126661725 @default.
- W3167996871 hasConceptScore W3167996871C159467904 @default.
- W3167996871 hasConceptScore W3167996871C161790260 @default.
- W3167996871 hasConceptScore W3167996871C178790620 @default.
- W3167996871 hasConceptScore W3167996871C181500209 @default.
- W3167996871 hasConceptScore W3167996871C184779094 @default.
- W3167996871 hasConceptScore W3167996871C185592680 @default.
- W3167996871 hasConceptScore W3167996871C192562407 @default.
- W3167996871 hasConceptScore W3167996871C198503264 @default.
- W3167996871 hasConceptScore W3167996871C204530211 @default.
- W3167996871 hasConceptScore W3167996871C2778689049 @default.
- W3167996871 hasConceptScore W3167996871C32909587 @default.
- W3167996871 hasConceptScore W3167996871C49040817 @default.
- W3167996871 hasConceptScore W3167996871C59061564 @default.
- W3167996871 hasConceptScore W3167996871C62520636 @default.
- W3167996871 hasConceptScore W3167996871C6260449 @default.
- W3167996871 hasConceptScore W3167996871C71240020 @default.
- W3167996871 hasConceptScore W3167996871C75473681 @default.
- W3167996871 hasConceptScore W3167996871C84114770 @default.
- W3167996871 hasConceptScore W3167996871C97292510 @default.
- W3167996871 hasConceptScore W3167996871C97355855 @default.
- W3167996871 hasLocation W31679968711 @default.
- W3167996871 hasLocation W31679968712 @default.
- W3167996871 hasLocation W31679968713 @default.
- W3167996871 hasOpenAccess W3167996871 @default.
- W3167996871 hasPrimaryLocation W31679968711 @default.
- W3167996871 hasRelatedWork W1965227126 @default.
- W3167996871 hasRelatedWork W1989692008 @default.
- W3167996871 hasRelatedWork W2076364111 @default.
- W3167996871 hasRelatedWork W2112106051 @default.
- W3167996871 hasRelatedWork W2899084033 @default.
- W3167996871 hasRelatedWork W2949568156 @default.
- W3167996871 hasRelatedWork W2950083444 @default.
- W3167996871 hasRelatedWork W2951305430 @default.
- W3167996871 hasRelatedWork W2953298349 @default.
- W3167996871 hasRelatedWork W3037016114 @default.
- W3167996871 isParatext "false" @default.
- W3167996871 isRetracted "false" @default.
- W3167996871 magId "3167996871" @default.
- W3167996871 workType "article" @default.