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• W3168505909 abstract "We measured the reaction kinetics of the electrochemical reduction of CO2 to formate on Pd/C and evaluated several proposed mechanisms, by comparing model-described and observed rates of formation of HCOO– and H2 as a function of several parameters (pH2, pCO2, and potential). An α-/β-hydride mechanism, based on an α-hydride phase active for CO2 reduction and a β-hydride Pd-phase active for hydrogen evolution, described the experimental data of our and other laboratories reported in the literature satisfactorily. After parametrization, using a data set including only H2, this mechanism also predicted the outcome of D2 isotope labeling experiments correctly. Analyses of the results indicate that the α-/β-hydride ratio and hydride formation rate are key factors affecting the formate production rate and the selectivity, thereby identifying areas for further (spectroscopic) studies and mechanism validation." @default.
• W3168505909 created "2021-06-22" @default.
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• W3168505909 date "2021-05-28" @default.
• W3168505909 modified "2023-10-18" @default.
• W3168505909 title "Mechanism and Micro Kinetic Model for Electroreduction of CO₂ on Pd/C: The Role of Different Palladium Hydride Phases" @default.
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• W3168505909 doi "https://doi.org/10.1021/acscatal.1c01325" @default.
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