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• W3168732724 abstract "Copolymerization between lactones and vinyl monomers has significant implications for the synthesis of new polymeric materials; however, a highly reactive cyclic monomer, e.g., ε-caprolactone (CL), leads to a copolymeric product but with a complex structure remaining to be elucidated. Herein, we present cooligomerizations of γ-butyrolactone (γBL), a low-polymerizable cyclic monomer, with (meth)acrylates catalyzed by an N-heterocyclic carbene (NHC) under conditions in which no reaction occurs in the absence of either comonomer. Several experimental studies indicate that the product is not a hybrid cooligomer with an ester linkage in the main chain but a graft cooligomer. The reaction mechanism involves the generation of the γBL enolate by the NHC to initiate oligomerizations of γBL and (meth)acrylates followed by the transesterification of oligo (γBL) with an ester unit of (meth)acrylates. These results prompted us to investigate the previously reported structure of copolymer of CL and methyl methacrylate obtained by a phosphazene base catalyst. The hydrolysis experiment revealed that the copolymeric product turned out not to be a hybrid random copolymer." @default.
• W3168732724 created "2021-06-22" @default.
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• W3168732724 date "2021-07-01" @default.
• W3168732724 modified "2023-10-16" @default.
• W3168732724 title "Cooligomerization of γ-butyrolactone with (meth)acrylates catalyzed by N-heterocyclic carbene: Low possibility of hybrid copolymerization" @default.
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• W3168732724 doi "https://doi.org/10.1016/j.polymer.2021.123953" @default.
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