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• W3169196175 endingPage "108734" @default.
• W3169196175 startingPage "108734" @default.
• W3169196175 abstract "An alkali-metal–lanthanide (AM–Ln)-embedded 19-tungsto-2-selenate derivative [H2N(CH3)2]8Na[CeNa(H2O)4(OH) WO(H2O)(B-α-SeW9O33)2]·18H2O (1) was synthesized by a self-assembly reaction of Na2WO4·2H2O, Na2SeO3, Ce(NO3)3·6H2O, C2H7N·HCl and 2,6-pyridinedicarboxylic acid in the mixed solvent of water and N,N-dimethylformamide (DMF) (v:v = 8: 2). The polyoxoanion of 1 is constructed by a semilunar [Se2W19O68]14− fragment sandwiching an AM–Ln [CeNa(H2O)4(OH)]3+ dinuclear cluster. The [Se2W19O68]14− unit comprises two trivacant [B-α-SeW9O33]8− moieties and a central {WO6} bridging group, displaying an open configuration for grasping additional metal groups. Moreover, 1 was assembled with carboxyl-functionalized multi-walled carbon nanotube (CMWCNT) to fabricate the 1@CMWCNT composite, and was further modified onto glass carbon electrode (GCE) to construct 1@CMWCNT-GCE electrochemical sensor (ECS) for the detection of uric acid (UA), generating a low detection limit of 1.69 μmol/L for UA. Notably, this work expands the application of polyoxometalate-based composite materials on detecting biomolecules." @default.
• W3169196175 created "2021-06-22" @default.
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• W3169196175 date "2021-08-01" @default.
• W3169196175 modified "2023-10-16" @default.
• W3169196175 title "Alkali metal–lanthanide co-encapsulated 19-tungsto-2-selenate derivative and its electrochemical detection of uric acid" @default.
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• W3169196175 doi "https://doi.org/10.1016/j.inoche.2021.108734" @default.
• W3169196175 hasPublicationYear "2021" @default.
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