Matches in SemOpenAlex for { <https://semopenalex.org/work/W3169552664> ?p ?o ?g. }
- W3169552664 endingPage "13687" @default.
- W3169552664 startingPage "13677" @default.
- W3169552664 abstract "We develop a novel theory for the impedance response of reversible electron transfer reactions under the influence of migration–diffusion coupling. Theory accounts for the influence of the supporting electrolyte, electroactive species, solvent, metal, and the interfacial electric field accounting underscreening. This semimicroscopic formalism is based on a modified electrode surface boundary constraint, which circumvents the essential nonlinearity in the Nernst–Planck equation. The interfacial electric field determines the kinetics of formation of compact electric double layer (C-EDL) embedded with electroactive species and influence the mass transport. This kinetics is governed by an intrinsic C-EDL formation resistance (RH), solution resistance (RΩ), and the extent of ion packing dependent on electrolyte composition. Theory unravels a characteristic ohmic-migration frequency, ω* = D/LMΩ2, a prerequisite for the outer sphere electron transfer step. A dimensionless migration–diffusion coupling number δM is unriddled, which quantifies the extent of migration contribution dependent on the potentials at IHP (ϕ1), OHP (ϕ2), diffuse layer (ϕDL), ion size-corrected screening length, charge on electroactive species, interfacial diffusivity, and RH. The magnitude of impedance (in low-frequency regime) evinces an anomalous nonmonotonic variation with ionic strength. Finally, theory accredits us to understand the underscreening-induced anomalies in migration–diffusion-controlled impedance response." @default.
- W3169552664 created "2021-06-22" @default.
- W3169552664 creator A5033798081 @default.
- W3169552664 creator A5076717795 @default.
- W3169552664 date "2021-06-15" @default.
- W3169552664 modified "2023-09-28" @default.
- W3169552664 title "Semimicroscopic Theory for Underscreening-Induced Anomalous Migration–Diffusion Coupling" @default.
- W3169552664 cites W1572786381 @default.
- W3169552664 cites W1966958553 @default.
- W3169552664 cites W1983155054 @default.
- W3169552664 cites W1986218990 @default.
- W3169552664 cites W1989925383 @default.
- W3169552664 cites W1991943102 @default.
- W3169552664 cites W1996742438 @default.
- W3169552664 cites W2007681550 @default.
- W3169552664 cites W2013888815 @default.
- W3169552664 cites W2024537965 @default.
- W3169552664 cites W2028325083 @default.
- W3169552664 cites W2035355112 @default.
- W3169552664 cites W2036090490 @default.
- W3169552664 cites W2047084687 @default.
- W3169552664 cites W2053536428 @default.
- W3169552664 cites W2055836755 @default.
- W3169552664 cites W2060528125 @default.
- W3169552664 cites W2066787346 @default.
- W3169552664 cites W2069298714 @default.
- W3169552664 cites W2070709253 @default.
- W3169552664 cites W2079585558 @default.
- W3169552664 cites W2086060006 @default.
- W3169552664 cites W2093282906 @default.
- W3169552664 cites W2124848012 @default.
- W3169552664 cites W2131264865 @default.
- W3169552664 cites W2146590404 @default.
- W3169552664 cites W2150094083 @default.
- W3169552664 cites W2315812262 @default.
- W3169552664 cites W2325347753 @default.
- W3169552664 cites W2336176490 @default.
- W3169552664 cites W2396502916 @default.
- W3169552664 cites W2580724977 @default.
- W3169552664 cites W2585585541 @default.
- W3169552664 cites W2618870667 @default.
- W3169552664 cites W2619514696 @default.
- W3169552664 cites W2762932284 @default.
- W3169552664 cites W2999802675 @default.
- W3169552664 cites W3044773437 @default.
- W3169552664 cites W3082164331 @default.
- W3169552664 cites W350305068 @default.
- W3169552664 cites W4244054492 @default.
- W3169552664 doi "https://doi.org/10.1021/acs.jpcc.1c03316" @default.
- W3169552664 hasPublicationYear "2021" @default.
- W3169552664 type Work @default.
- W3169552664 sameAs 3169552664 @default.
- W3169552664 citedByCount "7" @default.
- W3169552664 countsByYear W31695526642021 @default.
- W3169552664 countsByYear W31695526642022 @default.
- W3169552664 countsByYear W31695526642023 @default.
- W3169552664 crossrefType "journal-article" @default.
- W3169552664 hasAuthorship W3169552664A5033798081 @default.
- W3169552664 hasAuthorship W3169552664A5076717795 @default.
- W3169552664 hasConcept C121332964 @default.
- W3169552664 hasConcept C123669783 @default.
- W3169552664 hasConcept C145148216 @default.
- W3169552664 hasConcept C147789679 @default.
- W3169552664 hasConcept C159467904 @default.
- W3169552664 hasConcept C17525397 @default.
- W3169552664 hasConcept C178790620 @default.
- W3169552664 hasConcept C184501600 @default.
- W3169552664 hasConcept C185592680 @default.
- W3169552664 hasConcept C192562407 @default.
- W3169552664 hasConcept C26873012 @default.
- W3169552664 hasConcept C60799052 @default.
- W3169552664 hasConcept C62520636 @default.
- W3169552664 hasConcept C68801617 @default.
- W3169552664 hasConcept C69357855 @default.
- W3169552664 hasConcept C97355855 @default.
- W3169552664 hasConceptScore W3169552664C121332964 @default.
- W3169552664 hasConceptScore W3169552664C123669783 @default.
- W3169552664 hasConceptScore W3169552664C145148216 @default.
- W3169552664 hasConceptScore W3169552664C147789679 @default.
- W3169552664 hasConceptScore W3169552664C159467904 @default.
- W3169552664 hasConceptScore W3169552664C17525397 @default.
- W3169552664 hasConceptScore W3169552664C178790620 @default.
- W3169552664 hasConceptScore W3169552664C184501600 @default.
- W3169552664 hasConceptScore W3169552664C185592680 @default.
- W3169552664 hasConceptScore W3169552664C192562407 @default.
- W3169552664 hasConceptScore W3169552664C26873012 @default.
- W3169552664 hasConceptScore W3169552664C60799052 @default.
- W3169552664 hasConceptScore W3169552664C62520636 @default.
- W3169552664 hasConceptScore W3169552664C68801617 @default.
- W3169552664 hasConceptScore W3169552664C69357855 @default.
- W3169552664 hasConceptScore W3169552664C97355855 @default.
- W3169552664 hasFunder F4320334771 @default.
- W3169552664 hasIssue "24" @default.
- W3169552664 hasLocation W31695526641 @default.
- W3169552664 hasOpenAccess W3169552664 @default.
- W3169552664 hasPrimaryLocation W31695526641 @default.
- W3169552664 hasRelatedWork W2023714012 @default.
- W3169552664 hasRelatedWork W2026593768 @default.