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• W3169745097 startingPage "9757" @default.
• W3169745097 abstract "The development of nonprecious catalysts for hydrogenation of organic molecules is of great importance in heterogeneous catalysis. Herein, we report a series of N-doped hollow carbon frameworks encompassing cobalt nanoparticles (denoted as Co@NHF-900) constructed as a new kind of reusable catalyst for this purpose by pyrolysis of ZIF-8@Co–dopamine under Ar atmospheres. Notably, the framework of ZIF-8 is essential for efficient catalyst by providing a carbon framework to support Co–dopamine. The experimental results reveal that the ZIF-8 renders a large hollow place within the catalysts, allowing the enrichment of the substrate and windows of the hollow structure and the ease of mass transfer of products during the reaction. All of the virtues made Co@NHF-900 a good candidate for hydrogenation of quinolines with high activity (TOF value of 119 h–1, which is several times than that of akin catalysts) and chemoselectivity." @default.
• W3169745097 created "2021-06-22" @default.
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• W3169745097 date "2021-06-11" @default.
• W3169745097 modified "2023-10-14" @default.
• W3169745097 title "Encapsulating Cobalt into N-Doping Hollow Frameworks for Efficient Cascade Catalysis" @default.
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• W3169745097 doi "https://doi.org/10.1021/acs.inorgchem.1c01063" @default.
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• W3169745097 hasPublicationYear "2021" @default.
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