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• W3169918499 abstract "• The density of o-xylene/fullerene C 60 solutions on the boiling line was investigated. • Concentration dependences of all studied thermal properties have extremum points. • Fluctuation theory of liquids was applied to explain structural changes in solutions. This paper presents the experimental data for the thermal properties of fullerene C 60 / o-xylene solutions over a wide range of state parameters. The density was experimentally measured within a fullerene mass concentration range of 0–0.55% and a temperature range 273 K − 353 K. It was shown that the additives of fullerene C 60 reduced the density of o-xylene in the concentration range from 0 to (0.05 ± 0.01) wt.%. The temperature and concentration dependences of the isothermal compressibility and density fluctuations were analyzed. It was demonstrated that the temperature dependences of the density fluctuations show up as practically equidistant lines. This fact can be explained due to thermodynamically similar behavior of fullerene C 60 / o-xylene solutions and pure o-xylene. We found that the concentration dependences of the isothermal compressibility and density fluctuations in the concentration range of fullerene 0 ≤ w C6 ≤ 0.2% have zones of extremal changes. The zones coincide in the concentration range of fullerene with a zone of extreme decrease in the density. In our opinion, the reason of a nonmonotonous behavior of the thermal properties of fullerene C 60 / o-xylene solutions is the effect of fullerene on the density fluctuations of the base liquid as well as a quasicrystalline structure of a liquid phase." @default.
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• W3169918499 date "2021-09-01" @default.
• W3169918499 modified "2023-10-13" @default.
• W3169918499 title "On the nonmonotonous behavior of the thermal properties of fullerene C60 / o-xylene solutions" @default.
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• W3169918499 doi "https://doi.org/10.1016/j.molliq.2021.116629" @default.
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