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- W3170106545 abstract "Zinc oxide (ZnO) nanostructures have become the foremost prevalent metal oxide materials for technological applications due to their tunable optical properties. However, a simple, cheap and green method is required for the mass production of these nanostructures. In the present investigation ball-milling technique was used to tune the band gap of ZnO nanocrystallites. Samples were synthesized using metallic Zn powder and distilled water via wet-milling followed by dry-milling. The crystallite size of the ZnO samples were determined in the range of 24.9 – 22.0 nm depending on the dry milling time. UV-vis absorbance measurements and Kubelka-Munk theory were used to calculate the band gap of the ZnO nanocrystallites. The energy band gap of the samples was successfully tuned in the range of 3.15 - 3.02 eV depending on the nanocrystallite size. This behavior was explained by the surface states and energy traps on the band edge, created by delocalization of molecular orbitals." @default.
- W3170106545 created "2021-06-22" @default.
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- W3170106545 date "2022-03-01" @default.
- W3170106545 modified "2023-09-25" @default.
- W3170106545 title "Band Gap Engineering of ZnO Nanocrystallites Prepared via Ball-Milling" @default.
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- W3170106545 doi "https://doi.org/10.2339/politeknik.647702" @default.
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