Matches in SemOpenAlex for { <https://semopenalex.org/work/W3170454797> ?p ?o ?g. }
Showing items 1 to 100 of
100
with 100 items per page.
- W3170454797 endingPage "2660" @default.
- W3170454797 startingPage "2654" @default.
- W3170454797 abstract "Abstract The first alkali metal amidozincate hydroxides Na 3 [Zn(NH 2 ) 4 ](OH) and Na 3 [Zn(NH 2 ) 3 ](OH) 2 were obtained from supercritical ammonia under ammonobasic conditions at 823 K and 250 MPa, and 623 K and 159 MPa, respectively. Crystal structures have been refined against single crystal X‐ray diffraction intensity data. Coordination environments of the cations as well as the rather open crystal structure and low density of Na 3 [Zn(NH 2 ) 4 ](OH) suggest the initial formation of a monoammoniate, prior loss of ammonia during depressurizing and recovery of the product. While Na 3 [Zn(NH 2 ) 4 ](OH) contains mutually isolated amidozincate ions next to hydroxide ions, Na 3 [Zn(NH 2 ) 3 ](OH) 2 is the first amidozincate realizing a condensation of the complex anionic substructure so far. Both compounds are regarded possible intermediates in an ammonothermal zinc nitride synthesis and give insights into the action of impurities during ammonothermal processes. Raman spectroscopic measurements support the assignment of amide and hydroxide groups." @default.
- W3170454797 created "2021-06-22" @default.
- W3170454797 creator A5004177821 @default.
- W3170454797 creator A5017854395 @default.
- W3170454797 creator A5057727949 @default.
- W3170454797 creator A5073656082 @default.
- W3170454797 date "2021-06-12" @default.
- W3170454797 modified "2023-10-18" @default.
- W3170454797 title "Ammonothermal Synthesis and Characterization of First Amidozincate Hydroxides" @default.
- W3170454797 cites W1609742702 @default.
- W3170454797 cites W1939906140 @default.
- W3170454797 cites W1966662854 @default.
- W3170454797 cites W1968017028 @default.
- W3170454797 cites W1969819598 @default.
- W3170454797 cites W2002427803 @default.
- W3170454797 cites W2005771365 @default.
- W3170454797 cites W2015975792 @default.
- W3170454797 cites W2033750398 @default.
- W3170454797 cites W2041481698 @default.
- W3170454797 cites W2042008609 @default.
- W3170454797 cites W2042047863 @default.
- W3170454797 cites W2060510804 @default.
- W3170454797 cites W2079429027 @default.
- W3170454797 cites W2086161399 @default.
- W3170454797 cites W2086899657 @default.
- W3170454797 cites W2131350133 @default.
- W3170454797 cites W2331943839 @default.
- W3170454797 cites W2789382402 @default.
- W3170454797 cites W2949091287 @default.
- W3170454797 cites W2952157619 @default.
- W3170454797 cites W3100990693 @default.
- W3170454797 cites W3170454797 @default.
- W3170454797 cites W4205726323 @default.
- W3170454797 doi "https://doi.org/10.1002/ejic.202100348" @default.
- W3170454797 hasPublicationYear "2021" @default.
- W3170454797 type Work @default.
- W3170454797 sameAs 3170454797 @default.
- W3170454797 citedByCount "2" @default.
- W3170454797 countsByYear W31704547972021 @default.
- W3170454797 crossrefType "journal-article" @default.
- W3170454797 hasAuthorship W3170454797A5004177821 @default.
- W3170454797 hasAuthorship W3170454797A5017854395 @default.
- W3170454797 hasAuthorship W3170454797A5057727949 @default.
- W3170454797 hasAuthorship W3170454797A5073656082 @default.
- W3170454797 hasConcept C115624301 @default.
- W3170454797 hasConcept C118419359 @default.
- W3170454797 hasConcept C120665830 @default.
- W3170454797 hasConcept C121332964 @default.
- W3170454797 hasConcept C145148216 @default.
- W3170454797 hasConcept C178790620 @default.
- W3170454797 hasConcept C179104552 @default.
- W3170454797 hasConcept C185592680 @default.
- W3170454797 hasConcept C194760766 @default.
- W3170454797 hasConcept C198091228 @default.
- W3170454797 hasConcept C2775896084 @default.
- W3170454797 hasConcept C2776066698 @default.
- W3170454797 hasConcept C2776382133 @default.
- W3170454797 hasConcept C2779227376 @default.
- W3170454797 hasConcept C40003534 @default.
- W3170454797 hasConcept C535196362 @default.
- W3170454797 hasConcept C8010536 @default.
- W3170454797 hasConceptScore W3170454797C115624301 @default.
- W3170454797 hasConceptScore W3170454797C118419359 @default.
- W3170454797 hasConceptScore W3170454797C120665830 @default.
- W3170454797 hasConceptScore W3170454797C121332964 @default.
- W3170454797 hasConceptScore W3170454797C145148216 @default.
- W3170454797 hasConceptScore W3170454797C178790620 @default.
- W3170454797 hasConceptScore W3170454797C179104552 @default.
- W3170454797 hasConceptScore W3170454797C185592680 @default.
- W3170454797 hasConceptScore W3170454797C194760766 @default.
- W3170454797 hasConceptScore W3170454797C198091228 @default.
- W3170454797 hasConceptScore W3170454797C2775896084 @default.
- W3170454797 hasConceptScore W3170454797C2776066698 @default.
- W3170454797 hasConceptScore W3170454797C2776382133 @default.
- W3170454797 hasConceptScore W3170454797C2779227376 @default.
- W3170454797 hasConceptScore W3170454797C40003534 @default.
- W3170454797 hasConceptScore W3170454797C535196362 @default.
- W3170454797 hasConceptScore W3170454797C8010536 @default.
- W3170454797 hasFunder F4320320879 @default.
- W3170454797 hasIssue "26" @default.
- W3170454797 hasLocation W31704547971 @default.
- W3170454797 hasOpenAccess W3170454797 @default.
- W3170454797 hasPrimaryLocation W31704547971 @default.
- W3170454797 hasRelatedWork W1985344818 @default.
- W3170454797 hasRelatedWork W2018922446 @default.
- W3170454797 hasRelatedWork W2022914918 @default.
- W3170454797 hasRelatedWork W2028843163 @default.
- W3170454797 hasRelatedWork W2031090729 @default.
- W3170454797 hasRelatedWork W2035898100 @default.
- W3170454797 hasRelatedWork W2055861732 @default.
- W3170454797 hasRelatedWork W2089983838 @default.
- W3170454797 hasRelatedWork W2091736361 @default.
- W3170454797 hasRelatedWork W2152566655 @default.
- W3170454797 hasVolume "2021" @default.
- W3170454797 isParatext "false" @default.
- W3170454797 isRetracted "false" @default.
- W3170454797 magId "3170454797" @default.
- W3170454797 workType "article" @default.