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- W3171271135 abstract "Sulfur particles with a conductive polymer coating of poly(3,4-ethylene dioxythiophene) “PEDOT” were prepared by dielectric barrier discharge (DBD) plasma technology under atmospheric conditions (low temperature, ambient pressure). We report a solvent-free, low-cost, low-energy-consumption, safe, and low-risk process to make the material development and production compatible for sustainable technologies. Different coating protocols were developed to produce PEDOT-coated sulfur powders with electrical conductivity in the range of 10–8–10–5 S/cm. The raw sulfur powder (used as the reference) and (low-, optimum-, high-) PEDOT-coated sulfur powders were used to assemble lithium–sulfur (Li–S) cells with a high sulfur loading of ∼4.5 mg/cm2. Long-term galvanostatic cycling at C/10 for 100 cycles showed that the capacity fade was mitigated by ∼30% for the cells containing the optimum-PEDOT-coated sulfur in comparison to the reference Li–S cells with raw sulfur. Rate capability, cyclic voltammetry, and electrochemical impedance analyzes confirmed the improved behavior of the PEDOT-coated sulfur as an active material for lithium–sulfur batteries. The Li–S cells containing optimum-PEDOT-coated sulfur showed the highest reproducibility of their electrochemical properties. A wide variety of bulk and surface characterization methods including conductivity analysis, X-ray diffraction (XRD), scanning electron microscopy (SEM), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), and NMR spectroscopy were used to explain the chemical features and the superior behavior of Li–S cells using the optimum-PEDOT-coated sulfur material. Moreover, postmortem [SEM and Brunauer–Emmett–Teller (BET)] analyzes of uncoated and coated samples allowed us to exclude any significant effect at the electrode scale even after 70 cycles." @default.
- W3171271135 created "2021-06-22" @default.
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- W3171271135 date "2021-06-08" @default.
- W3171271135 modified "2023-10-17" @default.
- W3171271135 title "Dielectric Barrier Discharge (DBD) Plasma Coating of Sulfur for Mitigation of Capacity Fade in Lithium–Sulfur Batteries" @default.
- W3171271135 cites W1973290079 @default.
- W3171271135 cites W1977928242 @default.
- W3171271135 cites W1984650160 @default.
- W3171271135 cites W1985334529 @default.
- W3171271135 cites W1987722945 @default.
- W3171271135 cites W1999456033 @default.
- W3171271135 cites W1999957941 @default.
- W3171271135 cites W2009273624 @default.
- W3171271135 cites W2009860903 @default.
- W3171271135 cites W2010302203 @default.
- W3171271135 cites W2010739682 @default.
- W3171271135 cites W2012769703 @default.
- W3171271135 cites W2015201520 @default.
- W3171271135 cites W2016270680 @default.
- W3171271135 cites W2024658802 @default.
- W3171271135 cites W2024718224 @default.
- W3171271135 cites W2025424087 @default.
- W3171271135 cites W2037170640 @default.
- W3171271135 cites W2040576787 @default.
- W3171271135 cites W2049797652 @default.
- W3171271135 cites W2050911969 @default.
- W3171271135 cites W2051815385 @default.
- W3171271135 cites W2057587650 @default.
- W3171271135 cites W2057858310 @default.
- W3171271135 cites W2072228205 @default.
- W3171271135 cites W2074003099 @default.
- W3171271135 cites W2087001279 @default.
- W3171271135 cites W2090997613 @default.
- W3171271135 cites W2105027340 @default.
- W3171271135 cites W2111437752 @default.
- W3171271135 cites W2125658152 @default.
- W3171271135 cites W2125848420 @default.
- W3171271135 cites W2132172114 @default.
- W3171271135 cites W2132312776 @default.
- W3171271135 cites W2132665922 @default.
- W3171271135 cites W2135080619 @default.
- W3171271135 cites W2143612810 @default.
- W3171271135 cites W2158501890 @default.
- W3171271135 cites W2162275035 @default.
- W3171271135 cites W2164087645 @default.
- W3171271135 cites W2167753636 @default.
- W3171271135 cites W2276475940 @default.
- W3171271135 cites W2313604584 @default.
- W3171271135 cites W2326232602 @default.
- W3171271135 cites W2328166017 @default.
- W3171271135 cites W2335138902 @default.
- W3171271135 cites W2507616561 @default.
- W3171271135 cites W2520019442 @default.
- W3171271135 cites W2546456907 @default.
- W3171271135 cites W2555879592 @default.
- W3171271135 cites W2556915756 @default.
- W3171271135 cites W2567205822 @default.
- W3171271135 cites W2601537074 @default.
- W3171271135 cites W2604862259 @default.
- W3171271135 cites W2612538434 @default.
- W3171271135 cites W2612686288 @default.
- W3171271135 cites W2736911336 @default.
- W3171271135 cites W2749984104 @default.
- W3171271135 cites W2753279140 @default.
- W3171271135 cites W2768131873 @default.
- W3171271135 cites W2801966259 @default.
- W3171271135 cites W2811181082 @default.
- W3171271135 cites W2907793174 @default.
- W3171271135 cites W2945850079 @default.
- W3171271135 cites W2947078204 @default.
- W3171271135 cites W2967943101 @default.
- W3171271135 cites W3005104996 @default.
- W3171271135 cites W3011438184 @default.
- W3171271135 cites W3014782089 @default.
- W3171271135 cites W3029357396 @default.
- W3171271135 cites W3082976031 @default.
- W3171271135 cites W3112427713 @default.
- W3171271135 cites W3129115126 @default.
- W3171271135 cites W4236930778 @default.
- W3171271135 cites W4239902730 @default.
- W3171271135 cites W4251680482 @default.
- W3171271135 doi "https://doi.org/10.1021/acsami.1c04069" @default.
- W3171271135 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34100584" @default.
- W3171271135 hasPublicationYear "2021" @default.
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