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• W3171391346 startingPage "6805" @default.
• W3171391346 abstract "CO2 conversion to valuable chemicals and fuels at ambient temperature and atmospheric pressure using a sustainable energy source is an attractive but challenging task. Herein, Zr-thiamine is pyrolyzed with urea under N2 atmosphere to prepare Zr-thiamine modified carbon nitride (Zr-Thia/g-CN) catalyst. The catalyst exhibits optimum Lewis acidity and basicity to produce excellent cyclic carbonate yields by the insertion reaction of CO2 into epoxide on a large scale under neat conditions in the absence of any cocatalyst under traditional thermal catalysis in 6 h. The catalyst exhibits similar cyclic carbonate yield under simulated light (250 W Hg lamp, λ > 360 nm) in 24 h and, most importantly, under sunlight in 12 h in the presence of a low amount of cocatalyst (2.5 mol % with respect to epoxide) under ambient temperature, 1 bar pressure, and neat conditions. The catalyst is efficiently recycled up to 5 cycles in traditional thermal catalysis and photocatalytic conditions. The structure–activity relationship is established, and the reaction mechanism is proposed with the help of CO2 adsorption, CO2 temperature-programmed desorption techniques, acidity–basicity measurements, optoelectronic properties, control reactions, and catalytic activity data. The development of a single catalyst for catalyzing the same reaction under traditional thermal catalytic and sustainable photocatalytic conditions will attract researchers of different disciplines." @default.
• W3171391346 created "2021-06-22" @default.
• W3171391346 creator A5007946809 @default.
• W3171391346 creator A5021199389 @default.
• W3171391346 creator A5055710087 @default.
• W3171391346 date "2021-05-27" @default.
• W3171391346 modified "2023-10-06" @default.
• W3171391346 title "Graphitic Carbon Nitride Modified with Zr-Thiamine Complex for Efficient Photocatalytic CO₂ Insertion to Epoxide: Comparison with Traditional Thermal Catalysis" @default.
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• W3171391346 doi "https://doi.org/10.1021/acsanm.1c00887" @default.
• W3171391346 hasPublicationYear "2021" @default.
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