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• W3172116816 endingPage "111511" @default.
• W3172116816 startingPage "111511" @default.
• W3172116816 abstract "With biofuels market expanding, amines, as an important compound class in biofuels, are attracting increasing attention. The pyrolysis of n-propylamine (NPA) was studied in a flow tube using tunable synchrotron photoionization and molecular-beam mass spectrometry techniques. 28 and 30 species, including nitrogenous compounds and hydrocarbons, were identified and quantified at 30 and 760 Torr, respectively. 1,3-Cyclopentadiene, 1,4-pentadiene, 2-methyl-1,3-butadiene and benzene, were newly detected compared with previous studies of methylamine and ethylamine. HCN, NH3, N2 and methanimine were detected as the dominant nitrogenous products. Moreover, minor aliphatic and unsaturated amines were also identified, such as methylamine, ethylamine and acetaldimine. Ethylene achieved at the highest level among hydrocarbon products. With the pressure increasing, the onset temperature of NPA pyrolysis shifts towards low temperature region and NPA decomposes faster. A comprehensive detailed kinetic model involving 405 species and 2668 reactions was developed with reasonable predictions. According to rate-of-production analysis, H-abstractions, especially at Cα position of NPA, are the major consumption pathways of NPA. In addition, unimolecular reaction breaking Cα-Cβ bond is the important consumption channel of NPA at 30 Torr, while its positive effect is seriously weakened at 760 Torr. The H-abstraction at Cα (NPA+HCH3CH2CHNH2+H2) plays a leading role for NPA consumption at 760 Torr. The reactions, CH3+CH3=C2H5+H and CH3CHCHNH2+HCH2CHCHNH2+H2, tend to present inhibiting effects on NPA consumption at 30 and 760 Torr, respectively. These results could provide a theoretical basis for further combustion kinetic studies of biofuels and amine fuels." @default.
• W3172116816 created "2021-06-22" @default.
• W3172116816 creator A5025823762 @default.
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• W3172116816 date "2021-10-01" @default.
• W3172116816 modified "2023-10-13" @default.
• W3172116816 title "Pyrolysis investigation of n-propylamine with synchrotron photoionization and molecular-beam mass spectrometry" @default.
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• W3172116816 cites W1965106118 @default.
• W3172116816 cites W1966078314 @default.
• W3172116816 cites W1968313783 @default.
• W3172116816 cites W1974811616 @default.
• W3172116816 cites W1977799318 @default.
• W3172116816 cites W1984746227 @default.
• W3172116816 cites W1991629012 @default.
• W3172116816 cites W1991799120 @default.
• W3172116816 cites W1994093737 @default.
• W3172116816 cites W1996441017 @default.
• W3172116816 cites W1996772623 @default.
• W3172116816 cites W1999685827 @default.
• W3172116816 cites W2003012870 @default.
• W3172116816 cites W2007870981 @default.
• W3172116816 cites W2009526721 @default.
• W3172116816 cites W2009816513 @default.
• W3172116816 cites W2011487598 @default.
• W3172116816 cites W2012746759 @default.
• W3172116816 cites W2017101498 @default.
• W3172116816 cites W2017202176 @default.
• W3172116816 cites W2019564537 @default.
• W3172116816 cites W2023706981 @default.
• W3172116816 cites W2033638126 @default.
• W3172116816 cites W2042616896 @default.
• W3172116816 cites W2042760042 @default.
• W3172116816 cites W2047167950 @default.
• W3172116816 cites W2051091963 @default.
• W3172116816 cites W2053286315 @default.
• W3172116816 cites W2055746106 @default.
• W3172116816 cites W2079346192 @default.
• W3172116816 cites W2088285213 @default.
• W3172116816 cites W2093371483 @default.
• W3172116816 cites W2093432260 @default.
• W3172116816 cites W2111596229 @default.
• W3172116816 cites W2114761001 @default.
• W3172116816 cites W2117732072 @default.
• W3172116816 cites W2168319023 @default.
• W3172116816 cites W2173331310 @default.
• W3172116816 cites W2320825233 @default.
• W3172116816 cites W2321364666 @default.
• W3172116816 cites W2332433944 @default.
• W3172116816 cites W2417683073 @default.
• W3172116816 cites W2464314123 @default.
• W3172116816 cites W2470202358 @default.
• W3172116816 cites W2473464321 @default.
• W3172116816 cites W2526829883 @default.
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• W3172116816 cites W2899375609 @default.
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• W3172116816 cites W2921257921 @default.
• W3172116816 cites W2951260261 @default.
• W3172116816 cites W2952463948 @default.
• W3172116816 cites W2964343685 @default.
• W3172116816 cites W2968018372 @default.
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• W3172116816 doi "https://doi.org/10.1016/j.combustflame.2021.111511" @default.
• W3172116816 hasPublicationYear "2021" @default.
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