Matches in SemOpenAlex for { <https://semopenalex.org/work/W3172422433> ?p ?o ?g. }
- W3172422433 endingPage "82" @default.
- W3172422433 startingPage "82" @default.
- W3172422433 abstract "A series of heterometallic GdIII-VIV compounds were synthesized by the reaction of VOSO4·3H2O with cyclobutane-1,1-dicarboxylic acid salts M2(cbdc) (M = Na, Rb, Cs). The new compounds were formed by [Gd(VO)2(cbdc)4(H2O)8]− trinuclear anionic units that were similar in composition but differed in structure, depending on the nature of the alkali metal cation incorporated in the crystal structure of the compound. In the case of Na+, the {GdV2}− units were characterized by identical V···Gd distances and were linked into the 1D-polymeric chain [NaGd(VO)2(cbdc)4(H2O)10]n (1). In the systems with Rb+ and Cs+, the V···Gd distances were different, and the {GdV2}− units were linked into the 3D-framework {[RbGd(VO)2(cbdc)4(H2O)10]·2.5H2O}n (2) and the octanuclear molecule {[CsGd(VO)2(cbdc)4(H2O)11]·5H2O}2 (3), respectively. According to dc-magnetic measurements, the VIV and GdIII ions were ferromagnetically coupled in compound 1 (JVGd = 0.163 ± 0.008 cm−1), while in compounds 2 and 3, ferro- and weak antiferromagnetic exchange interactions were observed (JVGd = 0.989 ± 0.028 and −0.089 ± 0.008 cm−1 for 2, 0.656 ± 0.009 and −0.050 ± 0.004 cm−1 for 3). Analysis of the EPR spectra of 1 revealed the presence of weak magnetic anisotropy of GdIII ions (D ~ 0.08 cm−1 and E/D ~ 0.1–0.15). Ac-susceptibility measurements showed an occurrence the field-induced slow relaxation of magnetization in 1–3." @default.
- W3172422433 created "2021-06-22" @default.
- W3172422433 creator A5006326134 @default.
- W3172422433 creator A5025791693 @default.
- W3172422433 creator A5031393579 @default.
- W3172422433 creator A5050894526 @default.
- W3172422433 creator A5056067121 @default.
- W3172422433 creator A5062854810 @default.
- W3172422433 creator A5070743713 @default.
- W3172422433 creator A5070771627 @default.
- W3172422433 creator A5073425350 @default.
- W3172422433 date "2021-06-03" @default.
- W3172422433 modified "2023-10-10" @default.
- W3172422433 title "Effect of the Alkaline Metal Ion on the Crystal Structure and Magnetic Properties of Heterometallic GdIII-VIV Complexes Based on Cyclobutane-1,1-Dicarboxylate Anions" @default.
- W3172422433 cites W1997439464 @default.
- W3172422433 cites W2032679771 @default.
- W3172422433 cites W2039803942 @default.
- W3172422433 cites W2040902125 @default.
- W3172422433 cites W2046080123 @default.
- W3172422433 cites W2052312990 @default.
- W3172422433 cites W2052763839 @default.
- W3172422433 cites W2059205366 @default.
- W3172422433 cites W2063264867 @default.
- W3172422433 cites W2068413078 @default.
- W3172422433 cites W2086160352 @default.
- W3172422433 cites W2088417328 @default.
- W3172422433 cites W2094683017 @default.
- W3172422433 cites W2116591174 @default.
- W3172422433 cites W2117867509 @default.
- W3172422433 cites W2129660849 @default.
- W3172422433 cites W2132454074 @default.
- W3172422433 cites W2135560704 @default.
- W3172422433 cites W2141481560 @default.
- W3172422433 cites W2146051607 @default.
- W3172422433 cites W2177402492 @default.
- W3172422433 cites W2230728100 @default.
- W3172422433 cites W2299627883 @default.
- W3172422433 cites W2314879305 @default.
- W3172422433 cites W2320706634 @default.
- W3172422433 cites W2490757556 @default.
- W3172422433 cites W2507176797 @default.
- W3172422433 cites W2590124860 @default.
- W3172422433 cites W2594409807 @default.
- W3172422433 cites W2594716782 @default.
- W3172422433 cites W2601130839 @default.
- W3172422433 cites W2730356666 @default.
- W3172422433 cites W2739703142 @default.
- W3172422433 cites W2767370525 @default.
- W3172422433 cites W2781353440 @default.
- W3172422433 cites W2791343620 @default.
- W3172422433 cites W2791570612 @default.
- W3172422433 cites W2800219761 @default.
- W3172422433 cites W2803373982 @default.
- W3172422433 cites W2805507690 @default.
- W3172422433 cites W2808058011 @default.
- W3172422433 cites W2876939363 @default.
- W3172422433 cites W2884611339 @default.
- W3172422433 cites W2898059106 @default.
- W3172422433 cites W2899223577 @default.
- W3172422433 cites W2900666459 @default.
- W3172422433 cites W2943725711 @default.
- W3172422433 cites W2944990674 @default.
- W3172422433 cites W2945450057 @default.
- W3172422433 cites W2945577108 @default.
- W3172422433 cites W2951372844 @default.
- W3172422433 cites W2964218910 @default.
- W3172422433 cites W2995851878 @default.
- W3172422433 cites W3003671424 @default.
- W3172422433 cites W3004374416 @default.
- W3172422433 cites W3021260537 @default.
- W3172422433 cites W3042506244 @default.
- W3172422433 cites W3114517802 @default.
- W3172422433 cites W3122460602 @default.
- W3172422433 cites W3127635285 @default.
- W3172422433 cites W2963773665 @default.
- W3172422433 doi "https://doi.org/10.3390/magnetochemistry7060082" @default.
- W3172422433 hasPublicationYear "2021" @default.
- W3172422433 type Work @default.
- W3172422433 sameAs 3172422433 @default.
- W3172422433 citedByCount "2" @default.
- W3172422433 countsByYear W31724224332023 @default.
- W3172422433 crossrefType "journal-article" @default.
- W3172422433 hasAuthorship W3172422433A5006326134 @default.
- W3172422433 hasAuthorship W3172422433A5025791693 @default.
- W3172422433 hasAuthorship W3172422433A5031393579 @default.
- W3172422433 hasAuthorship W3172422433A5050894526 @default.
- W3172422433 hasAuthorship W3172422433A5056067121 @default.
- W3172422433 hasAuthorship W3172422433A5062854810 @default.
- W3172422433 hasAuthorship W3172422433A5070743713 @default.
- W3172422433 hasAuthorship W3172422433A5070771627 @default.
- W3172422433 hasAuthorship W3172422433A5073425350 @default.
- W3172422433 hasBestOaLocation W31724224331 @default.
- W3172422433 hasConcept C115624301 @default.
- W3172422433 hasConcept C121332964 @default.
- W3172422433 hasConcept C145148216 @default.
- W3172422433 hasConcept C155355069 @default.
- W3172422433 hasConcept C16889073 @default.
- W3172422433 hasConcept C178790620 @default.