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- W3172784920 abstract "Structures and vibrational spectra of l-prolinium l-proline chloride (I), l-prolinium l-proline bromide (II) and l-prolinium l-proline iodide (III) were analyzed at 100K, 200K and room temperature (RT). The salts (I) and (II) are isostructural and crystallize in the tetragonal space group P41212, Z=8 at RT and in orthorhombic P212121, Z=8 at 100K and 200K. The salt (III) is orthorhombic, space group P212121, Z=4 at all three temperatures. The O⋅⋅⋅O distances in l-prolinium l-proline dimeric cations are equal to 2.464(3) Å (I), 2.456(3) Å (II) and 2.456(4) Å (III) at RT. The presence of strong hydrogen bonds in the crystal structures is reflected in the infrared spectra. The influence of symmetry on second harmonic activity is discussed." @default.
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- W3172784920 date "2021-11-01" @default.
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- W3172784920 title "l-Prolinium l-proline halogenides: a comparison of the respective chloride, bromide and iodide salts" @default.
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- W3172784920 doi "https://doi.org/10.1016/j.molstruc.2021.130851" @default.
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