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• W3172949003 startingPage "115292" @default.
• W3172949003 abstract "A new sterically hindered Schiff base ligand (SN-NNDMB) was synthesized from meso-1,2-diphenyl ethylenediamine (meso-stien) and 4-N,N′-dimethylaminobenzaldehyde. Its structure was determined by single-crystal X-ray diffraction data. The crystal structure of the organic ligand was found to be triclinic, space group P-1 with a = 6.1407(8) Å, b = 8.8372(12) Å, c = 12.0006(15) Å, α = 103.882(7)°, β = 95.325(8)°, γ = 91.082(7)°, F(0 0 0) = 254, Dc = 1.253 Mg/m3, µ = 0.571 mm−1, R = 0.0399, and wR = 0.1019. Co, Ni, Cu and Zn complexes of SN-NNDMB were also prepared and characterized by elemental analysis, IR-, mass-, NMR- and electronic- spectra, magnetic moment, molar conductance, powder XRD, and TGA. The obtained results show that the Schiff base ligand acts as a bidentate, coordinated through the azomethine nitrogen atoms. According to the biotest such as Antimicrobial, DNA binding, DNA cleaving, Anti-tubercular, Anticancer, and SOD-like activity, the compounds showed better activity after chelation. The Cu(II)-SN-NNDMB complex showed the highest bioactive potential amonst the analyzed compounds." @default.
• W3172949003 created "2021-06-22" @default.
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• W3172949003 date "2021-09-01" @default.
• W3172949003 modified "2023-09-25" @default.
• W3172949003 title "Synthesis, characterization and biological studies of a sterically hindered symmetrical nitrogen donor ligand and its metal complexes" @default.
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• W3172949003 doi "https://doi.org/10.1016/j.poly.2021.115292" @default.
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