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• W3173204932 endingPage "11783" @default.
• W3173204932 startingPage "11775" @default.
• W3173204932 abstract "Transition-metal complexes bearing labile ligands can be difficult to isolate and study in solution because of unwanted dinucleation or ligand substitution reactions. Metal–organic frameworks (MOFs) provide a unique matrix that allows site isolation and stabilization of well-defined transition-metal complexes that may be of importance as moieties for gas adsorption or catalysis. Herein we report the development of an in situ anion metathesis strategy that facilitates the postsynthetic modification of Cu(I) complexes appended to a porous, crystalline MOF. By exchange of coordinated chloride for weakly coordinating anions in the presence of carbon monoxide (CO) or ethylene, a series of labile MOF-appended Cu(I) complexes featuring CO or ethylene ligands are prepared and structurally characterized using X-ray crystallography. These complexes have an uncommon trigonal planar geometry because of the absence of coordinating solvents. The porous host framework allows small and moderately sized molecules to access the isolated Cu(I) sites and displace the “place-holder” CO ligand, mirroring the ligand-exchange processes involved in Cu-centered catalysis." @default.
• W3173204932 created "2021-07-05" @default.
• W3173204932 creator A5000211125 @default.
• W3173204932 creator A5017113466 @default.
• W3173204932 creator A5027976787 @default.
• W3173204932 creator A5060018496 @default.
• W3173204932 creator A5083099327 @default.
• W3173204932 date "2021-06-23" @default.
• W3173204932 modified "2023-10-05" @default.
• W3173204932 title "Single-Crystal-to-Single-Crystal Transformations of Metal–Organic-Framework-Supported, Site-Isolated Trigonal-Planar Cu(I) Complexes with Labile Ligands" @default.
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• W3173204932 doi "https://doi.org/10.1021/acs.inorgchem.1c00849" @default.
• W3173204932 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34160208" @default.

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