FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3173728042> ?p ?o ?g. }

• W3173728042 endingPage "30467" @default.
• W3173728042 startingPage "30458" @default.
• W3173728042 abstract "Liquid ammonia is considered a sustainable liquid fuel and an easily transportable carrier of hydrogen energy; however, its synthesis processes are energy-consuming, high cost, and low yield rate. Herein, we report the electrocatalytic reduction of nitrate (NO3-) (ERN) to ammonia (NH3) with nickel phosphide (Ni2P) used as a noble metal-free cathode. Ni2P with (111) facet was grown in situ on nickel foam (NFP), which was regarded as a self-supporting cathode for ERN to synthesis NH3 with high yield rate (0.056 mmol h-1 mg-1) and superior faradaic efficiency of 99.23%. The derived atomic H (*H), verified by a quenching experiment and an electron spin resonance (ESR) technique, effectively enhanced the high selectivity for NH3 generation. DFT calculations indicated that *NO3 was deoxygenated to *NO2 and *NO, and *NO was subsequently hydrogenated with *H to generate NH3 with an energy releasing process (ΔG < 0). OLEMS also proved that NO was the merely gas intermediate. NFP exhibited the unique superhydrophilic surface, metallic properties, low impedance, and abundant surface sites, favorable for adsorption of NO3-, generation of *H, and then hydrogenation of NO3-. Hence, NFP cathode showed high selectivity for NH3 (89.1%) in ERN. NFP with long-term stability and low energy consumption provides a facile strategy for synthesis of NH3 and elimination of NO3- contamination." @default.
• W3173728042 created "2021-07-05" @default.
• W3173728042 creator A5006644615 @default.
• W3173728042 creator A5017575617 @default.
• W3173728042 creator A5032678772 @default.
• W3173728042 creator A5084961529 @default.
• W3173728042 creator A5090617343 @default.
• W3173728042 date "2021-06-23" @default.
• W3173728042 modified "2023-10-02" @default.
• W3173728042 title "Selective Electrocatalytic Reduction of Nitrate to Ammonia with Nickel Phosphide" @default.
• W3173728042 cites W142780377 @default.
• W3173728042 cites W1965302556 @default.
• W3173728042 cites W1977812371 @default.
• W3173728042 cites W1982360987 @default.
• W3173728042 cites W1983134936 @default.
• W3173728042 cites W2003624206 @default.
• W3173728042 cites W2004108257 @default.
• W3173728042 cites W2030919818 @default.
• W3173728042 cites W2050104692 @default.
• W3173728042 cites W2061949585 @default.
• W3173728042 cites W2066623343 @default.
• W3173728042 cites W2071217022 @default.
• W3173728042 cites W2074894104 @default.
• W3173728042 cites W2088845946 @default.
• W3173728042 cites W2096744674 @default.
• W3173728042 cites W2117794813 @default.
• W3173728042 cites W2134557319 @default.
• W3173728042 cites W2137776484 @default.
• W3173728042 cites W2151201269 @default.
• W3173728042 cites W2156809317 @default.
• W3173728042 cites W2158376193 @default.
• W3173728042 cites W2284266154 @default.
• W3173728042 cites W2312634087 @default.
• W3173728042 cites W2466909181 @default.
• W3173728042 cites W2495744501 @default.
• W3173728042 cites W2506987273 @default.
• W3173728042 cites W2513690577 @default.
• W3173728042 cites W2556334122 @default.
• W3173728042 cites W2564515886 @default.
• W3173728042 cites W2582660055 @default.
• W3173728042 cites W2757359630 @default.
• W3173728042 cites W2770934075 @default.
• W3173728042 cites W2787012572 @default.
• W3173728042 cites W2789166653 @default.
• W3173728042 cites W2800327896 @default.
• W3173728042 cites W2803724286 @default.
• W3173728042 cites W2804705815 @default.
• W3173728042 cites W2884398478 @default.
• W3173728042 cites W2885736519 @default.
• W3173728042 cites W2885761419 @default.
• W3173728042 cites W2887542968 @default.
• W3173728042 cites W2889299098 @default.
• W3173728042 cites W2895515877 @default.
• W3173728042 cites W2901677037 @default.
• W3173728042 cites W2946792384 @default.
• W3173728042 cites W2966416845 @default.
• W3173728042 cites W2971891187 @default.
• W3173728042 cites W2973141153 @default.
• W3173728042 cites W2991036799 @default.
• W3173728042 cites W2997118807 @default.
• W3173728042 cites W3006689796 @default.
• W3173728042 cites W3009104606 @default.
• W3173728042 cites W3019546165 @default.
• W3173728042 cites W3042269744 @default.
• W3173728042 cites W3045634212 @default.
• W3173728042 doi "https://doi.org/10.1021/acsami.0c22338" @default.
• W3173728042 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34159788" @default.
• W3173728042 hasPublicationYear "2021" @default.
• W3173728042 type Work @default.
• W3173728042 sameAs 3173728042 @default.
• W3173728042 citedByCount "49" @default.
• W3173728042 countsByYear W31737280422021 @default.
• W3173728042 countsByYear W31737280422022 @default.
• W3173728042 countsByYear W31737280422023 @default.
• W3173728042 crossrefType "journal-article" @default.
• W3173728042 hasAuthorship W3173728042A5006644615 @default.
• W3173728042 hasAuthorship W3173728042A5017575617 @default.
• W3173728042 hasAuthorship W3173728042A5032678772 @default.
• W3173728042 hasAuthorship W3173728042A5084961529 @default.
• W3173728042 hasAuthorship W3173728042A5090617343 @default.
• W3173728042 hasConcept C111335779 @default.
• W3173728042 hasConcept C147789679 @default.
• W3173728042 hasConcept C17525397 @default.
• W3173728042 hasConcept C178790620 @default.
• W3173728042 hasConcept C179104552 @default.
• W3173728042 hasConcept C185592680 @default.
• W3173728042 hasConcept C191897082 @default.
• W3173728042 hasConcept C192562407 @default.
• W3173728042 hasConcept C2524010 @default.
• W3173728042 hasConcept C2776382133 @default.
• W3173728042 hasConcept C2776384668 @default.
• W3173728042 hasConcept C2780654602 @default.
• W3173728042 hasConcept C33923547 @default.
• W3173728042 hasConcept C33989665 @default.
• W3173728042 hasConcept C504270822 @default.
• W3173728042 hasConcept C52859227 @default.
• W3173728042 hasConceptScore W3173728042C111335779 @default.
• W3173728042 hasConceptScore W3173728042C147789679 @default.

• next