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- W3174107437 abstract "The first systematic study of simple nitronate nucleophiles in iridium-catalyzed allylic alkylation is described. Using a tol-BINAP-modified π-allyliridium C,O-benzoate catalyst, α,α-disubstituted nitronates substitute racemic branched alkyl-substituted allylic acetates, thus providing entry to β-stereogenic α-quaternary primary amines. DFT calculations reveal early transition states that render the reaction less sensitive to steric effects and distinct trans-effects of diastereomeric chiral-at-iridium π-allyl complexes that facilitate formation of congested tertiary-quaternary C-C bonds." @default.
- W3174107437 created "2021-07-05" @default.
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- W3174107437 date "2021-06-21" @default.
- W3174107437 modified "2023-10-06" @default.
- W3174107437 title "Enantioselective Iridium-Catalyzed Allylation of Nitroalkanes: Entry to β-Stereogenic α-Quaternary Primary Amines" @default.
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- W3174107437 doi "https://doi.org/10.1021/jacs.1c05212" @default.
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