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• W3174330106 endingPage "9267" @default.
• W3174330106 startingPage "9263" @default.
• W3174330106 abstract "Metal-rich chalcogenides with unique network architectures are rare but are of considerable interest because of their intriguing physical properties. In this work, a novel quaternary thioantimonate, Rb2CuSb7S12, has been discovered by a facile surfactant-thermal reaction. It crystallizes monoclinic space group P1̅ (No. 2) and exhibits a unique Sb-rich three-dimensional (3D) [CuSb7S12]2– framework surrounded by charge-compensating Rb+ cations. It is interesting to note that the Cu/Sb ratio of Rb2CuSb7S12 represents the lowest limit in the quaternary A/Cu/Sb/Q (A = alkali metals; Q = chalcogen) system. Moreover, Rb2CuSb7S12 shows rapid response and good reproducibility based on the photoelectrochemical tests. This study opens up opportunities for discovering the desirable physical properties in metal-rich chalcogenides." @default.
• W3174330106 created "2021-07-05" @default.
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• W3174330106 date "2021-06-24" @default.
• W3174330106 modified "2023-10-16" @default.
• W3174330106 title "Rb₂CuSb₇S₁₂: Quaternary Antimony-Rich Semiconductor Featuring a Three-Dimensional Open Framework and Exhibiting an Intriguing Photocurrent Response" @default.
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• W3174330106 doi "https://doi.org/10.1021/acs.inorgchem.1c01278" @default.
• W3174330106 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34165289" @default.
• W3174330106 hasPublicationYear "2021" @default.
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