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• W3174652014 abstract "Abstract The Ag 2− x Na x ZnP 2 O 7 ( x = 0, 1, and 2) materials are prepared using the solid–solid method followed by heat treatment. The investigated samples are characterized by combining X‐ray powder diffraction and electrical impedance spectroscopy techniques. The Rietveld refinement of the X‐ray diffraction (XRD) pattern revealed that these Ag 2 ZnP 2 O 7 , AgNaZnP 2 O 7 , and Na 2 ZnP 2 O 7 compounds are indexed in the tetragonal system with the P4 2 / n space group. Their dielectric properties are measured in the frequency and temperature ranges of 200–10 7 Hz and 419–518 K, respectively. In these compounds, the dielectric relaxation can be described by a Cole–Cole model. The frequency dependence of the conductivity is interpreted in terms of Jonscher's law. For the three compounds, the activation energy for conduction has a different value compared to the activation energy for the relaxation process. This indicates that the conduction in the compound is not predicted by the simple hopping model. Then, the temperature dependence of the power‐law exponent(s) suggests that the non‐overlapping small polaron tunneling model is the dominant transport process in these materials. Moreover, the values of defect states N (EF) and the tunnel distance R W show the electrical performance of the Ag 2 ZnP 2 O 7 compound." @default.
• W3174652014 created "2021-07-05" @default.
• W3174652014 creator A5058167976 @default.
• W3174652014 creator A5059870613 @default.
• W3174652014 creator A5090715949 @default.
• W3174652014 date "2021-06-20" @default.
• W3174652014 modified "2023-10-17" @default.
• W3174652014 title "Dielectric Relaxation and Non‐Overlapping Small Polaron Tunneling Model Conduction Studies of Ag _2‐ <i> _x </i> Na <i> _x </i> ZnP ₂ O ₇ ( <i>x</i> = 0, 1, and 2) Materials" @default.
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• W3174652014 doi "https://doi.org/10.1002/crat.202100035" @default.
• W3174652014 hasPublicationYear "2021" @default.
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