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- W3174662200 abstract "The extreme corrosion at the melt line of glass tanks has been attributed to the Marangoni effect, with the driving force being glass currents driven by surface tension. It is challenging to use this model to completely describe upward drilling by gas bubbles, downward drilling by metals, and rapid dissolution of porous refractories. In 1975, Woldemar Weyl discussed how many properties of glass could be explained if the surface of glass had a viscosity lower than the bulk. This concept of surface viscosity is explored to describe refractory corrosion. A viscosity model is proposed where parameters can be modified for the surface as well as the bulk. The model uses the equation: η(T) = 1/(M(T-T0)exp(-E/(T-T0))), where the E term is linearly correlated to the coordination number of network bonds in the glass network, M is the ability for the structural units to rotate, and T0 is related to bonding in the glass not due to the network bonds. Accelerated corrosion of glass contact refractories in melting furnaces at the following locations: Melt line corrosion Corrosion at block joints and cracks Corrosion due to porosity in blocks Downward drilling due to metals Upward drilling due to bubbles High temperature regions High flow regions It will be discussed how the first 5 of these processes are highly affected by surface viscosity, and the challenges to reduce this accelerated corrosion." @default.
- W3174662200 created "2021-07-05" @default.
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- W3174662200 date "2021-06-22" @default.
- W3174662200 modified "2023-09-26" @default.
- W3174662200 title "SURFACE VISCOSITY AND THE MELTING OF GLASS" @default.
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- W3174662200 doi "https://doi.org/10.1002/9781119823056.ch1" @default.
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