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- W3174751712 abstract "Marine biological fouling has always been a hot research topic. In this study, silver @ cuprous oxide ([email protected]2O) core-shell nanoparticles were synthesized via in-situ synthesis method and developed an outstanding antibacterial activity. The bacteriostasis efficiency of [email protected]2O reached to 99% and 98% against Staphylococcus aureus and Pseudomonas aeruginosa, respectively. The minimum inhibitory concentration of [email protected]2O decreased from 113.6 μg/mL to 56.8 μg/mL compared with Cu2O. [email protected]2O had better antibacterial activity than Cu2O with lower content of Cu2O and was more environment friendly. The heterostructure formed at the interface between Ag and Cu2O promoted the separation and diffusion of photogenerated electron-hole pairs through the charge transfer channel and promoted the generation of reactive oxygen species. The outstanding antibacterial activity of [email protected]2O was strongly depended on the generation of the reactive oxygen species. Density functional theory and finite element method calculations demonstrated that the structure of core-shell improved photocatalytic efficiency. Additionally, synergetic effect of released Ag+ and Cu2+ also enhanced the bacteriostasis rate and the long-term antifouling performance in 60 days. Hence, the synthesized core-shell [email protected]2O can be applied as novel antifoulants in the marine field." @default.
- W3174751712 created "2021-07-05" @default.
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- W3174751712 date "2021-11-01" @default.
- W3174751712 modified "2023-10-17" @default.
- W3174751712 title "Charge transfer channels of silver @ cuprous oxide heterostructure core-shell nanoparticles strengthen high photocatalytic antibacterial activity" @default.
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- W3174751712 doi "https://doi.org/10.1016/j.jcis.2021.05.113" @default.
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