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• W3174894037 abstract "• Kinetic modelling of energy transfer requires state-to-state rate coefficients. • Accuracy of rates from method based upon scaling laws is limited. • Direct simulation of collisions provides better state-to-state rate coefficients. • Intermolecular forces and coupling of vibration modes are the key for accuracy. In this work we present a set of state-specific rate coefficients of processes of translational and vibrational energy exchange involving the asymmetric stretching mode of CO 2 molecules in gas phase. Vibration-Translation exchange is studied from thermal up to moderately high temperature regime (4000 K). For the Vibration–Vibration exchange the first ten asymmetric stretching energy levels are covered at room temperature. Rate coefficients are obtained simulating the collision dynamics by a full dimensional intermolecular potential obtained in a previous work. The data are intended for use in the kinetic modeling of gaseous mixtures containing CO 2 as a major component." @default.
• W3174894037 created "2021-07-05" @default.
• W3174894037 creator A5070740378 @default.
• W3174894037 creator A5086060513 @default.
• W3174894037 date "2021-09-01" @default.
• W3174894037 modified "2023-09-24" @default.
• W3174894037 title "Deactivation dynamics of carbon dioxide in gas phase at thermal and moderately high temperature regimes" @default.
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• W3174894037 doi "https://doi.org/10.1016/j.cplett.2021.138850" @default.
• W3174894037 hasPublicationYear "2021" @default.
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