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- W3175890295 abstract "Herein, we employed a molecular Ru(II) catalyst immobilized onto TiO2 particulates of (4,4′-Y2-bpy)RuII(CO)2Cl2 (RuP; Y = CH2PO(OH)2), as a hybrid catalyst system to secure the efficient and steady catalytic activity of a molecular bipyridyl Ru(II)-complex-based photocatalytic system for CO2 reduction. From a series of operando FTIR spectrochemical analyses, it was found that the TiO2-fixed molecular Ru(II) complex leads to efficient stabilization of the key monomeric intermediate, RuII-hydride (LRuII(H)(CO)2Cl), and suppresses the formation of polymeric Ru(II) complex (−(L(CO)2Ru–Ru(CO)2L)n−), which is a major deactivation product produced during photoreaction via the Ru–Ru dimeric route. Active promotion of the monomeric catalytic route in a hetero-binary system (IrPS + TiO2/RuP) that uses TiO2-bound Ru(II) complex as reduction catalyst led to highly increased activity as well as durability of photocatalytic behavior with respect to the homogeneous catalysis of free Ru(II) catalyst (IrPS + Ru(II) catalyst). This catalytic strategy produced maximal turnover numbers (TONs) of >4816 and >2228, respectively, for CO and HCOO– production in CO2-saturated N,N-dimethylformamide (DMF)/TEOA (16.7 vol % TEOA) solution containing a 0.1 M sacrificial electron donor." @default.
- W3175890295 created "2021-07-05" @default.
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- W3175890295 date "2021-07-01" @default.
- W3175890295 modified "2023-10-14" @default.
- W3175890295 title "A Hybrid Ru(II)/TiO<sub>2</sub> Catalyst for Steadfast Photocatalytic CO<sub>2</sub> to CO/Formate Conversion Following a Molecular Catalytic Route" @default.
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- W3175890295 doi "https://doi.org/10.1021/acs.inorgchem.1c00615" @default.
- W3175890295 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34196536" @default.
- W3175890295 hasPublicationYear "2021" @default.
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