Matches in SemOpenAlex for { <https://semopenalex.org/work/W3176752972> ?p ?o ?g. }
- W3176752972 endingPage "863" @default.
- W3176752972 startingPage "857" @default.
- W3176752972 abstract "As the scope of additive manufacturing broadens, interest has developed in 3D-printed objects that are derived from recyclable resins with chemical and mechanical tunability. Dynamic covalent bonds have the potential to not only increase the sustainability of 3D-printed objects, but also serve as reactive sites for postprinting derivatization. In this study, we use boronate esters as a key building block for the development of catalyst-free, 3D-printing resins with the ability to undergo room-temperature exchange at the cross-linking sites. The orthogonality of boronate esters is exploited in fast-curing, oxygen-tolerant thiol-ene resins in which the dynamic character of 3D-printed objects can be modulated by the addition of a static, covalent cross-linker with no room-temperature bond exchange. This allows the mechanical properties of printed parts to be varied between those of a traditional thermoset and a vitrimer. Objects printed with a hybrid dynamic/static resin exhibit a balance of structural stability (residual stress = 18%) and rapid exchange (characteristic relaxation time = 7 s), allowing for interfacial welding and postprinting functionalization. Modulation of the cross-linking density postprinting is enabled by selective hydrolysis of the boronate esters to generate networks with swelling capacities tunable from 1.3 to 3.3." @default.
- W3176752972 created "2021-07-05" @default.
- W3176752972 creator A5001435522 @default.
- W3176752972 creator A5006028538 @default.
- W3176752972 creator A5010990361 @default.
- W3176752972 creator A5019663765 @default.
- W3176752972 creator A5036216864 @default.
- W3176752972 creator A5044252746 @default.
- W3176752972 creator A5064340656 @default.
- W3176752972 creator A5070181837 @default.
- W3176752972 date "2021-06-23" @default.
- W3176752972 modified "2023-10-15" @default.
- W3176752972 title "Chemical and Mechanical Tunability of 3D-Printed Dynamic Covalent Networks Based on Boronate Esters" @default.
- W3176752972 cites W1963036046 @default.
- W3176752972 cites W2012016930 @default.
- W3176752972 cites W2017353202 @default.
- W3176752972 cites W2017741151 @default.
- W3176752972 cites W2048644480 @default.
- W3176752972 cites W2079296603 @default.
- W3176752972 cites W2085143384 @default.
- W3176752972 cites W2110429104 @default.
- W3176752972 cites W2125002848 @default.
- W3176752972 cites W2156110237 @default.
- W3176752972 cites W2266720690 @default.
- W3176752972 cites W2268908313 @default.
- W3176752972 cites W2278194135 @default.
- W3176752972 cites W2323861871 @default.
- W3176752972 cites W2427335962 @default.
- W3176752972 cites W2500889105 @default.
- W3176752972 cites W2589654725 @default.
- W3176752972 cites W2605049395 @default.
- W3176752972 cites W2605061198 @default.
- W3176752972 cites W2608588436 @default.
- W3176752972 cites W2615049565 @default.
- W3176752972 cites W2733697899 @default.
- W3176752972 cites W2761631495 @default.
- W3176752972 cites W2781765098 @default.
- W3176752972 cites W2785241767 @default.
- W3176752972 cites W2790786953 @default.
- W3176752972 cites W2795028566 @default.
- W3176752972 cites W2796144065 @default.
- W3176752972 cites W2800511327 @default.
- W3176752972 cites W2809333160 @default.
- W3176752972 cites W2884182729 @default.
- W3176752972 cites W2886154463 @default.
- W3176752972 cites W2890613432 @default.
- W3176752972 cites W2897832052 @default.
- W3176752972 cites W2902013963 @default.
- W3176752972 cites W2912101418 @default.
- W3176752972 cites W2912720184 @default.
- W3176752972 cites W2965539225 @default.
- W3176752972 cites W2972947395 @default.
- W3176752972 cites W2976130428 @default.
- W3176752972 cites W2979159125 @default.
- W3176752972 cites W2982502209 @default.
- W3176752972 cites W2984221450 @default.
- W3176752972 cites W2985118202 @default.
- W3176752972 cites W2985760152 @default.
- W3176752972 cites W2986980534 @default.
- W3176752972 cites W2990661326 @default.
- W3176752972 cites W2994442083 @default.
- W3176752972 cites W2997996048 @default.
- W3176752972 cites W3001267765 @default.
- W3176752972 cites W3002206259 @default.
- W3176752972 cites W3006489879 @default.
- W3176752972 cites W3010619035 @default.
- W3176752972 cites W3013006475 @default.
- W3176752972 cites W3016672182 @default.
- W3176752972 cites W3088423880 @default.
- W3176752972 cites W3098405603 @default.
- W3176752972 cites W3111668066 @default.
- W3176752972 cites W3129384159 @default.
- W3176752972 cites W3147842747 @default.
- W3176752972 cites W3157184183 @default.
- W3176752972 cites W3159913083 @default.
- W3176752972 cites W4235463652 @default.
- W3176752972 doi "https://doi.org/10.1021/acsmacrolett.1c00257" @default.
- W3176752972 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35549203" @default.
- W3176752972 hasPublicationYear "2021" @default.
- W3176752972 type Work @default.
- W3176752972 sameAs 3176752972 @default.
- W3176752972 citedByCount "35" @default.
- W3176752972 countsByYear W31767529722021 @default.
- W3176752972 countsByYear W31767529722022 @default.
- W3176752972 countsByYear W31767529722023 @default.
- W3176752972 crossrefType "journal-article" @default.
- W3176752972 hasAuthorship W3176752972A5001435522 @default.
- W3176752972 hasAuthorship W3176752972A5006028538 @default.
- W3176752972 hasAuthorship W3176752972A5010990361 @default.
- W3176752972 hasAuthorship W3176752972A5019663765 @default.
- W3176752972 hasAuthorship W3176752972A5036216864 @default.
- W3176752972 hasAuthorship W3176752972A5044252746 @default.
- W3176752972 hasAuthorship W3176752972A5064340656 @default.
- W3176752972 hasAuthorship W3176752972A5070181837 @default.
- W3176752972 hasConcept C127413603 @default.
- W3176752972 hasConcept C132976073 @default.
- W3176752972 hasConcept C159985019 @default.
- W3176752972 hasConcept C171359207 @default.