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• W3177988904 endingPage "1777" @default.
• W3177988904 startingPage "1764" @default.
• W3177988904 abstract "Abstract By matrix isolation in solid Ne and Kr, VO, VO 2 , and the complexes VO 2 (O 2 ) with one superoxo ligand and VO 2 (O 2 ) 2 with one superoxo and one neutral dioxygen ligand, as well as V 2 O 2 and V 2 O 4 have been generated. For VO 2 (O 2 ), transitions of five vibrational modes have been observed, and for VO 2 (O 2 ) 2 , transitions belonging to seven vibrational modes, confirming and extending former Ar matrix results. Attempts to stabilise the cyclic V(O 2 ) peroxide by use of the heavier Kr matrix were not successful. By accompanying MRCI calculations on VO 2 and V(O 2 ), vibrational frequencies have been determined. Furthermore, the investigation is assisted by density functional calculations with the TPSS functional. Possibly, also one vibrational transition of the VO 3 molecule has been observed." @default.
• W3177988904 created "2021-07-19" @default.
• W3177988904 creator A5039804927 @default.
• W3177988904 creator A5073407894 @default.
• W3177988904 date "2021-07-29" @default.
• W3177988904 modified "2023-09-25" @default.
• W3177988904 title "The Dioxygen Complexes of VO ₂" @default.
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• W3177988904 doi "https://doi.org/10.1002/zaac.202100156" @default.
• W3177988904 hasPublicationYear "2021" @default.
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