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- W3178010145 endingPage "22003" @default.
- W3178010145 startingPage "21997" @default.
- W3178010145 abstract "Abstract A tunable photocatalytic method is reported for anti ‐Markovnikov hydro‐ and aminooxygenation of unactivated alkenes using readily accessible ketoxime carbonates as the diverse functionalization reagents. Mechanistic studies reveal that this reaction is initiated through an energy‐transfer‐promoted N−O bond homolysis of ketoxime carbonates leading to alkoxylcarbonyloxyl and iminyl radicals under visible‐light photocatalysis, followed by the addition of alkoxylcarbonyloxyl radical to alkenes. By taking advantage of the different stability of the iminyl radicals, the generated carbon radical either abstracts a hydrogen atom from the media to form the anti ‐Markovnikov hydrooxygenation product, or it is trapped by the persistent iminyl radical to furnish the aminooxygenation product. Notably, this is the first example of direct hydrooxygenation of unactivated olefins with anti ‐Markovnikov regioselectivity involving an oxygen‐centered radical." @default.
- W3178010145 created "2021-07-19" @default.
- W3178010145 creator A5013127361 @default.
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- W3178010145 creator A5044785404 @default.
- W3178010145 creator A5061638439 @default.
- W3178010145 creator A5082610200 @default.
- W3178010145 date "2021-08-31" @default.
- W3178010145 modified "2023-10-15" @default.
- W3178010145 title "Photocatalytic <i>Anti</i> ‐Markovnikov Radical Hydro‐ and Aminooxygenation of Unactivated Alkenes Tuned by Ketoxime Carbonates" @default.
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- W3178010145 doi "https://doi.org/10.1002/anie.202107118" @default.