Matches in SemOpenAlex for { <https://semopenalex.org/work/W3178100706> ?p ?o ?g. }
- W3178100706 endingPage "20341" @default.
- W3178100706 startingPage "20331" @default.
- W3178100706 abstract "The multimetallic sulfur-framework catalytic site of biological nitrogenases allows the efficient conversion of dinitrogen (N2) to ammonia (NH3) under ambient conditions. Inspired by biological nitrogenases, a bimetallic sulfide material (FeWSx@FeWO4) was synthesized as a highly efficient N2 reduction (NRR) catalyst by sulfur substitution of the surface of FeWO4 nanoparticles. Thus prepared FeWSx@FeWO4 catalysts exhibit a relatively high NH3 production rate of 30.2 ug h−1 mg−1cat and a Faraday efficiency of 16.4 % at −0.45 V versus a reversible hydrogen electrode in a flow cell; these results have been confirmed via purified 15N2-isotopic labeling experiments. In situ Raman spectra and hydrazine reduction kinetics analysis revealed that the reduction of undissociated hydrazine intermediates (M-NH2-NH2) on the surface of the bimetallic sulfide catalyst is the rate-determing step for the NRR process. Therefore, this work can provide guidance for elucidating the structure–activity relationship of NRR catalysts." @default.
- W3178100706 created "2021-07-19" @default.
- W3178100706 creator A5020120173 @default.
- W3178100706 creator A5022256556 @default.
- W3178100706 creator A5026292768 @default.
- W3178100706 creator A5065183138 @default.
- W3178100706 creator A5066786495 @default.
- W3178100706 creator A5072753033 @default.
- W3178100706 creator A5074141445 @default.
- W3178100706 creator A5088775444 @default.
- W3178100706 creator A5091739958 @default.
- W3178100706 date "2021-08-06" @default.
- W3178100706 modified "2023-10-01" @default.
- W3178100706 title "Identification of M‐NH <sub>2</sub> ‐NH <sub>2</sub> Intermediate and Rate Determining Step for Nitrogen Reduction with Bioinspired Sulfur‐Bonded FeW Catalyst" @default.
- W3178100706 cites W1966558159 @default.
- W3178100706 cites W1970727467 @default.
- W3178100706 cites W1975564172 @default.
- W3178100706 cites W1987490818 @default.
- W3178100706 cites W2003431221 @default.
- W3178100706 cites W2010571276 @default.
- W3178100706 cites W2013072084 @default.
- W3178100706 cites W2014782995 @default.
- W3178100706 cites W2030908439 @default.
- W3178100706 cites W2043204689 @default.
- W3178100706 cites W2058836080 @default.
- W3178100706 cites W2059804857 @default.
- W3178100706 cites W2063917761 @default.
- W3178100706 cites W2071194190 @default.
- W3178100706 cites W2078353661 @default.
- W3178100706 cites W2079108335 @default.
- W3178100706 cites W2079916550 @default.
- W3178100706 cites W2080772314 @default.
- W3178100706 cites W2083510097 @default.
- W3178100706 cites W2087946802 @default.
- W3178100706 cites W2090341171 @default.
- W3178100706 cites W2090485175 @default.
- W3178100706 cites W2104684144 @default.
- W3178100706 cites W2116064505 @default.
- W3178100706 cites W2133766418 @default.
- W3178100706 cites W2156809317 @default.
- W3178100706 cites W2197327513 @default.
- W3178100706 cites W2305290835 @default.
- W3178100706 cites W2325627160 @default.
- W3178100706 cites W2326199030 @default.
- W3178100706 cites W2418943070 @default.
- W3178100706 cites W2529904852 @default.
- W3178100706 cites W2556334122 @default.
- W3178100706 cites W2583719179 @default.
- W3178100706 cites W2591686856 @default.
- W3178100706 cites W2592046628 @default.
- W3178100706 cites W2606639832 @default.
- W3178100706 cites W2612972784 @default.
- W3178100706 cites W2767966656 @default.
- W3178100706 cites W2797768937 @default.
- W3178100706 cites W2803729875 @default.
- W3178100706 cites W2851584547 @default.
- W3178100706 cites W2854019328 @default.
- W3178100706 cites W2886829405 @default.
- W3178100706 cites W2909267103 @default.
- W3178100706 cites W2909705737 @default.
- W3178100706 cites W2911443767 @default.
- W3178100706 cites W2914840694 @default.
- W3178100706 cites W2920912088 @default.
- W3178100706 cites W2922287547 @default.
- W3178100706 cites W2945223387 @default.
- W3178100706 cites W2946199134 @default.
- W3178100706 cites W2955640401 @default.
- W3178100706 cites W2969308506 @default.
- W3178100706 cites W2980571682 @default.
- W3178100706 cites W2980953107 @default.
- W3178100706 cites W2989786623 @default.
- W3178100706 cites W2999584513 @default.
- W3178100706 cites W3001208419 @default.
- W3178100706 cites W3029551610 @default.
- W3178100706 cites W3034300274 @default.
- W3178100706 cites W3103013862 @default.
- W3178100706 cites W4230804472 @default.
- W3178100706 cites W4235356326 @default.
- W3178100706 cites W4237476726 @default.
- W3178100706 cites W4237995377 @default.
- W3178100706 cites W4248822875 @default.
- W3178100706 cites W4249125801 @default.
- W3178100706 cites W4253609693 @default.
- W3178100706 cites W656628758 @default.
- W3178100706 doi "https://doi.org/10.1002/anie.202104918" @default.
- W3178100706 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/8456964" @default.
- W3178100706 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34245082" @default.
- W3178100706 hasPublicationYear "2021" @default.
- W3178100706 type Work @default.
- W3178100706 sameAs 3178100706 @default.
- W3178100706 citedByCount "55" @default.
- W3178100706 countsByYear W31781007062021 @default.
- W3178100706 countsByYear W31781007062022 @default.
- W3178100706 countsByYear W31781007062023 @default.
- W3178100706 crossrefType "journal-article" @default.
- W3178100706 hasAuthorship W3178100706A5020120173 @default.
- W3178100706 hasAuthorship W3178100706A5022256556 @default.
- W3178100706 hasAuthorship W3178100706A5026292768 @default.