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• W3178532869 endingPage "7318" @default.
• W3178532869 startingPage "7313" @default.
• W3178532869 abstract "A multifunctional O-phenyl thiocarbonyl (O(C═S)OPh) group was introduced in glycosylation reactions. This auxiliary group exhibits three features (1) C6-long-range participation effect, (2) relay activation, and (3) switchable promoter-controlled carbonylation, which enables the facile synthesis of both 6-deoxy glucoside and 6-alcohol glucoside. In addition, we successfully quantified the extent of the C6-acyl participation effect and developed its application toward the α-trisaccharide motif." @default.
• W3178532869 created "2021-07-19" @default.
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• W3178532869 date "2021-07-16" @default.
• W3178532869 modified "2023-10-18" @default.
• W3178532869 title "Thiocarbonyl as a Switchable Relay-Auxiliary Group in Carbohydrate Synthesis" @default.
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• W3178532869 doi "https://doi.org/10.1021/acs.orglett.1c01968" @default.
• W3178532869 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34269593" @default.
• W3178532869 hasPublicationYear "2021" @default.
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