Matches in SemOpenAlex for { <https://semopenalex.org/work/W3178693860> ?p ?o ?g. }
- W3178693860 endingPage "20406" @default.
- W3178693860 startingPage "20400" @default.
- W3178693860 abstract "Abstract Adsorptive separation of propylene/propane (C 3 H 6 /C 3 H 8 ) mixture is desired for its potential energy saving on replacing currently deployed and energy‐intensive cryogenic distillation. Realizing efficient C 3 H 6 /C 3 H 8 separation in the emerging hydrogen‐bonded organic frameworks (HOFs) is very challenging owing to the lack of functional sites for preferential gas binding. By virtue of crystal engineering, we herein report a functionalized HOF ( HOF‐16 ) with free ‐COOH sites for the efficient separation of C 3 H 6 /C 3 H 8 mixtures. Under ambient conditions, HOF‐16 shows a significant C 3 H 6 /C 3 H 8 uptake difference (by 76 %) and selectivity (5.4) in contrast to other carboxylic acid‐based HOFs. Modeling studies indicate that free ‐COOH groups together with the suitable pore confinement facilitate the recognition and high‐density packing of gas molecules. The separation performance of HOF‐16 was validated by breakthrough experiments. HOF‐16 is stable towards strong acidity and water." @default.
- W3178693860 created "2021-07-19" @default.
- W3178693860 creator A5034430149 @default.
- W3178693860 creator A5035646855 @default.
- W3178693860 creator A5036732242 @default.
- W3178693860 creator A5037372036 @default.
- W3178693860 creator A5040139098 @default.
- W3178693860 creator A5051473707 @default.
- W3178693860 creator A5056863791 @default.
- W3178693860 creator A5076574339 @default.
- W3178693860 creator A5078273951 @default.
- W3178693860 creator A5083206827 @default.
- W3178693860 date "2021-07-29" @default.
- W3178693860 modified "2023-10-11" @default.
- W3178693860 title "A Microporous Hydrogen‐Bonded Organic Framework for the Efficient Capture and Purification of Propylene" @default.
- W3178693860 cites W1961126151 @default.
- W3178693860 cites W1972357467 @default.
- W3178693860 cites W2000298832 @default.
- W3178693860 cites W2032127032 @default.
- W3178693860 cites W2049145344 @default.
- W3178693860 cites W2065367617 @default.
- W3178693860 cites W2079552584 @default.
- W3178693860 cites W2102410614 @default.
- W3178693860 cites W2113481168 @default.
- W3178693860 cites W2127106839 @default.
- W3178693860 cites W2148665247 @default.
- W3178693860 cites W2151985601 @default.
- W3178693860 cites W2313907882 @default.
- W3178693860 cites W2327441974 @default.
- W3178693860 cites W2339540635 @default.
- W3178693860 cites W2402426102 @default.
- W3178693860 cites W2460359349 @default.
- W3178693860 cites W2468089184 @default.
- W3178693860 cites W2471550346 @default.
- W3178693860 cites W2576867483 @default.
- W3178693860 cites W2579069397 @default.
- W3178693860 cites W2591366729 @default.
- W3178693860 cites W2607760541 @default.
- W3178693860 cites W2762912060 @default.
- W3178693860 cites W2765417707 @default.
- W3178693860 cites W2790308498 @default.
- W3178693860 cites W2791754381 @default.
- W3178693860 cites W2794391083 @default.
- W3178693860 cites W2794728674 @default.
- W3178693860 cites W2801568402 @default.
- W3178693860 cites W2811062389 @default.
- W3178693860 cites W2877882896 @default.
- W3178693860 cites W2891145874 @default.
- W3178693860 cites W2897241813 @default.
- W3178693860 cites W2897403085 @default.
- W3178693860 cites W2898261008 @default.
- W3178693860 cites W2898567034 @default.
- W3178693860 cites W2907398728 @default.
- W3178693860 cites W2913849030 @default.
- W3178693860 cites W2914798666 @default.
- W3178693860 cites W2920141431 @default.
- W3178693860 cites W2923732278 @default.
- W3178693860 cites W2924950089 @default.
- W3178693860 cites W2935426584 @default.
- W3178693860 cites W2935825491 @default.
- W3178693860 cites W2937512451 @default.
- W3178693860 cites W2944427781 @default.
- W3178693860 cites W2944918728 @default.
- W3178693860 cites W2946381111 @default.
- W3178693860 cites W2954033820 @default.
- W3178693860 cites W2964185417 @default.
- W3178693860 cites W2969524404 @default.
- W3178693860 cites W2979611469 @default.
- W3178693860 cites W2979837018 @default.
- W3178693860 cites W2980308203 @default.
- W3178693860 cites W2983039574 @default.
- W3178693860 cites W2990549441 @default.
- W3178693860 cites W2995856058 @default.
- W3178693860 cites W3003233427 @default.
- W3178693860 cites W3004356871 @default.
- W3178693860 cites W3009642335 @default.
- W3178693860 cites W3013858303 @default.
- W3178693860 cites W3014017543 @default.
- W3178693860 cites W3036541441 @default.
- W3178693860 cites W3041089874 @default.
- W3178693860 cites W3044744859 @default.
- W3178693860 cites W3046254670 @default.
- W3178693860 cites W3081154292 @default.
- W3178693860 cites W3082730859 @default.
- W3178693860 cites W3090222968 @default.
- W3178693860 cites W3091253856 @default.
- W3178693860 cites W3095332691 @default.
- W3178693860 cites W3118018085 @default.
- W3178693860 cites W3128008365 @default.
- W3178693860 cites W3129006223 @default.
- W3178693860 cites W3132333045 @default.
- W3178693860 cites W3144575346 @default.
- W3178693860 cites W3173325259 @default.
- W3178693860 cites W4232014550 @default.
- W3178693860 cites W4233471658 @default.
- W3178693860 cites W4234931833 @default.
- W3178693860 cites W4237261388 @default.
- W3178693860 cites W4243046620 @default.