FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3179698544> ?p ?o ?g. }

• W3179698544 abstract "Because of their closed shells, noble gas (Ng) atoms (Ng = Ne, Ar, Kr, and Xe) seldom take part in chemical reactions, yet finding such mechanisms not only is of scientific interest but also has practical significance. Following a recent work by Mayer et al. [Proc. Natl. Acad. Sci. U. S. A. 116, 8167–8172 (2019)] on the room temperature binding of Ar to a superelectrophilic boron site embedded in a negative ion complex, B12(CN)11−, we have systematically studied the effect of cluster size and terminal ligands on the interaction of Ng by focusing on B12X11(Ng) (X = H, CN, and BO) and B12X10(Ng)2 (X = CN and BO) whose stabilities are governed by the Wade–Mingos rule and on C5BX5(Ng) (X = H, F, and CN) and C4B2(CN)4(Ng)2 whose stabilities are governed by the Huckel’s aromaticity rule. Our conclusion, based on density functional theory, is that both the cluster size and the terminal ligands matter—the interaction between the cluster and the Ng atoms becomes stronger with increasing cluster size and the electron affinity of the terminal ligands. Our studies also led to a counter-intuitive finding—removing multiple terminal ligands can enable electrophilic centers to bind multiple Ng atoms simultaneously without compromising their binding strength." @default.
• W3179698544 created "2021-07-19" @default.
• W3179698544 creator A5012866011 @default.
• W3179698544 creator A5029507793 @default.
• W3179698544 creator A5049552092 @default.
• W3179698544 date "2021-07-01" @default.
• W3179698544 modified "2023-10-15" @default.
• W3179698544 title "Binding of noble gas atoms by superhalogens" @default.
• W3179698544 cites W1665393863 @default.
• W3179698544 cites W1968438687 @default.
• W3179698544 cites W1983436447 @default.
• W3179698544 cites W1984237478 @default.
• W3179698544 cites W2010861052 @default.
• W3179698544 cites W2012625181 @default.
• W3179698544 cites W2013449099 @default.
• W3179698544 cites W2023271753 @default.
• W3179698544 cites W2024017001 @default.
• W3179698544 cites W2032264514 @default.
• W3179698544 cites W2043038764 @default.
• W3179698544 cites W2051774577 @default.
• W3179698544 cites W2055913904 @default.
• W3179698544 cites W2086359553 @default.
• W3179698544 cites W2096747776 @default.
• W3179698544 cites W2097387863 @default.
• W3179698544 cites W2130918438 @default.
• W3179698544 cites W2131267323 @default.
• W3179698544 cites W2132525235 @default.
• W3179698544 cites W2279649462 @default.
• W3179698544 cites W2323579379 @default.
• W3179698544 cites W2327530295 @default.
• W3179698544 cites W2329412109 @default.
• W3179698544 cites W2335606392 @default.
• W3179698544 cites W2619169881 @default.
• W3179698544 cites W2737851344 @default.
• W3179698544 cites W2789462042 @default.
• W3179698544 cites W2806250317 @default.
• W3179698544 cites W2925998731 @default.
• W3179698544 cites W2950348578 @default.
• W3179698544 cites W2988202025 @default.
• W3179698544 cites W3021524372 @default.
• W3179698544 cites W4237580338 @default.
• W3179698544 cites W4240406016 @default.
• W3179698544 doi "https://doi.org/10.1063/5.0054621" @default.
• W3179698544 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34241393" @default.
• W3179698544 hasPublicationYear "2021" @default.
• W3179698544 type Work @default.
• W3179698544 sameAs 3179698544 @default.
• W3179698544 citedByCount "4" @default.
• W3179698544 countsByYear W31796985442022 @default.
• W3179698544 countsByYear W31796985442023 @default.
• W3179698544 crossrefType "journal-article" @default.
• W3179698544 hasAuthorship W3179698544A5012866011 @default.
• W3179698544 hasAuthorship W3179698544A5029507793 @default.
• W3179698544 hasAuthorship W3179698544A5049552092 @default.
• W3179698544 hasBestOaLocation W31796985441 @default.
• W3179698544 hasConcept C121332964 @default.
• W3179698544 hasConcept C121530826 @default.
• W3179698544 hasConcept C145148216 @default.
• W3179698544 hasConcept C147120987 @default.
• W3179698544 hasConcept C147597530 @default.
• W3179698544 hasConcept C152365726 @default.
• W3179698544 hasConcept C161790260 @default.
• W3179698544 hasConcept C164866538 @default.
• W3179698544 hasConcept C178790620 @default.
• W3179698544 hasConcept C184779094 @default.
• W3179698544 hasConcept C185592680 @default.
• W3179698544 hasConcept C199360897 @default.
• W3179698544 hasConcept C2780740876 @default.
• W3179698544 hasConcept C2781238429 @default.
• W3179698544 hasConcept C32909587 @default.
• W3179698544 hasConcept C41008148 @default.
• W3179698544 hasConcept C50027330 @default.
• W3179698544 hasConcept C501308230 @default.
• W3179698544 hasConcept C62520636 @default.
• W3179698544 hasConcept C71240020 @default.
• W3179698544 hasConcept C8010536 @default.
• W3179698544 hasConcept C93282013 @default.
• W3179698544 hasConceptScore W3179698544C121332964 @default.
• W3179698544 hasConceptScore W3179698544C121530826 @default.
• W3179698544 hasConceptScore W3179698544C145148216 @default.
• W3179698544 hasConceptScore W3179698544C147120987 @default.
• W3179698544 hasConceptScore W3179698544C147597530 @default.
• W3179698544 hasConceptScore W3179698544C152365726 @default.
• W3179698544 hasConceptScore W3179698544C161790260 @default.
• W3179698544 hasConceptScore W3179698544C164866538 @default.
• W3179698544 hasConceptScore W3179698544C178790620 @default.
• W3179698544 hasConceptScore W3179698544C184779094 @default.
• W3179698544 hasConceptScore W3179698544C185592680 @default.
• W3179698544 hasConceptScore W3179698544C199360897 @default.
• W3179698544 hasConceptScore W3179698544C2780740876 @default.
• W3179698544 hasConceptScore W3179698544C2781238429 @default.
• W3179698544 hasConceptScore W3179698544C32909587 @default.
• W3179698544 hasConceptScore W3179698544C41008148 @default.
• W3179698544 hasConceptScore W3179698544C50027330 @default.
• W3179698544 hasConceptScore W3179698544C501308230 @default.
• W3179698544 hasConceptScore W3179698544C62520636 @default.
• W3179698544 hasConceptScore W3179698544C71240020 @default.
• W3179698544 hasConceptScore W3179698544C8010536 @default.
• W3179698544 hasConceptScore W3179698544C93282013 @default.
• W3179698544 hasFunder F4320306084 @default.

• next