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- W3179804904 abstract "Catalytic pyrolysis is an effective method for converting biomass to value-added chemicals. However, the development of cost-effective catalysts remains a major challenge. In this study, a highly efficient bimetallic Pt–Ni catalyst (Pt to Ni ratio = 0:1, 2:1, 1:1, 1:2, 1:0) was fabricated and used for catalytic biomass pyrolysis upgrading into hydrocarbon-rich bio-oil with pyrolysis-gaschromatography × gaschromatography/mass spectrometry (Py-GC∗ GC/MS). The product yield and selectivity of upgraded bio-oil, thermal properties, kinetic and deactivation mechanisms were also determined to investigate the reaction mechanism. It was determined that Pt addition strengthened the NiO and alumina interaction and improved nickel dispersion, promoting CO hydrogenation. Bimetallic catalysts had a higher stability and activity owing to synergistic action of platinum and nickel on γ-Al2O3, and the surface oxygen vacancies were derived from the electron transfer of Pt to Ni and the higher number of super acid-base sites, which inhibited coke deposition. In addition, the higher valence Pt (Pt2+) in the catalyst was favorable for decarboxylation and hydrodecarbonylation reactions. Various metal ratios were employed, and the Pt–Ni/Al = 1:2 catalyst exhibited an excellent catalytic performance, achieving highest peak areas of desired hydrocarbons and aromatic hydrocarbons at 52.67% and 40.25%, respectively, and the lowest peak area of deposited coke at 7.26%, along with a 13.98% weightloss rate." @default.
- W3179804904 created "2021-07-19" @default.
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- W3179804904 creator A5084913798 @default.
- W3179804904 date "2021-08-01" @default.
- W3179804904 modified "2023-10-18" @default.
- W3179804904 title "Highly efficient catalytic pyrolysis of biomass vapors upgraded into jet fuel range hydrocarbon-rich bio-oil over a bimetallic Pt–Ni/γ-Al2O3 catalyst" @default.
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- W3179804904 cites W1980317218 @default.
- W3179804904 cites W1997018395 @default.
- W3179804904 cites W1997704681 @default.
- W3179804904 cites W1997810980 @default.
- W3179804904 cites W2013120668 @default.
- W3179804904 cites W2035373899 @default.
- W3179804904 cites W2045207481 @default.
- W3179804904 cites W2046487185 @default.
- W3179804904 cites W2047509749 @default.
- W3179804904 cites W2050306224 @default.
- W3179804904 cites W2052707614 @default.
- W3179804904 cites W2054476554 @default.
- W3179804904 cites W2062109849 @default.
- W3179804904 cites W2070893497 @default.
- W3179804904 cites W2075460637 @default.
- W3179804904 cites W2079467705 @default.
- W3179804904 cites W2095263282 @default.
- W3179804904 cites W2112994587 @default.
- W3179804904 cites W2142337008 @default.
- W3179804904 cites W2143844135 @default.
- W3179804904 cites W2145813022 @default.
- W3179804904 cites W2153419733 @default.
- W3179804904 cites W2160934486 @default.
- W3179804904 cites W2163503641 @default.
- W3179804904 cites W2272860423 @default.
- W3179804904 cites W2337833912 @default.
- W3179804904 cites W2411877529 @default.
- W3179804904 cites W2429452955 @default.
- W3179804904 cites W2513522328 @default.
- W3179804904 cites W2519932146 @default.
- W3179804904 cites W2536290156 @default.
- W3179804904 cites W2553128596 @default.
- W3179804904 cites W2604344434 @default.
- W3179804904 cites W2604481926 @default.
- W3179804904 cites W2616798925 @default.
- W3179804904 cites W2620722525 @default.
- W3179804904 cites W2657874755 @default.
- W3179804904 cites W2726125225 @default.
- W3179804904 cites W2741428948 @default.
- W3179804904 cites W2783217938 @default.
- W3179804904 cites W2789503504 @default.
- W3179804904 cites W2803794284 @default.
- W3179804904 cites W2892812247 @default.
- W3179804904 cites W2896964822 @default.
- W3179804904 cites W2897011679 @default.
- W3179804904 cites W2908206845 @default.
- W3179804904 cites W2913567478 @default.
- W3179804904 cites W2931414999 @default.
- W3179804904 cites W2936204253 @default.
- W3179804904 cites W2939459460 @default.
- W3179804904 cites W2971097925 @default.
- W3179804904 cites W2984062544 @default.
- W3179804904 cites W2985832062 @default.
- W3179804904 cites W2987786882 @default.
- W3179804904 cites W2989710948 @default.
- W3179804904 cites W2989721621 @default.
- W3179804904 cites W2990235957 @default.
- W3179804904 cites W2997310763 @default.
- W3179804904 cites W3005463253 @default.
- W3179804904 cites W3006979793 @default.
- W3179804904 cites W3019936259 @default.
- W3179804904 cites W3020535727 @default.
- W3179804904 cites W3028536798 @default.
- W3179804904 cites W3034167216 @default.
- W3179804904 cites W3045054719 @default.
- W3179804904 cites W3045972090 @default.
- W3179804904 cites W3048800138 @default.
- W3179804904 cites W3083908683 @default.
- W3179804904 cites W3085892358 @default.
- W3179804904 cites W3086612818 @default.
- W3179804904 cites W3087641242 @default.
- W3179804904 cites W3088399231 @default.
- W3179804904 cites W4237599933 @default.
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- W3179804904 doi "https://doi.org/10.1016/j.ijhydene.2021.06.082" @default.
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