Matches in SemOpenAlex for { <https://semopenalex.org/work/W3179985478> ?p ?o ?g. }
- W3179985478 endingPage "116963" @default.
- W3179985478 startingPage "116963" @default.
- W3179985478 abstract "The molar enthalpies of mixing (ΔmixHm) in the liquid potassium chloride-uranium(III) chloride mixtures have been measured with a Calvet-type high temperature microcalorimeter over the entire composition range at 1113 K. All the melts are characterized by negative enthalpies of mixing with a minimum value of about −17.5 kJ·mol−1. The minimum of the enthalpy of mixing is shifted towards the potassium chloride-rich compositions and located in the vicinity of xUCl3 ~ 0.40. The obtained results are discussed in terms of complexes formation in the liquid mixtures under investigation. Experimental mixing enthalpy data were used together with existing literature data in re-examination of KCl-UCl3 phase diagram. Analysis of the literature data on KCl-UCl3 phase diagram has indicated that all of them are not correct because the existence of K3UCl6 compound was ignored in spite of experimental facts pointing its existence. Reinterpretation of all existing data by CALPHAD method showed that the system under investigation is characterized by existence of K2UCl5 and K3UCl6 congruently melting compounds, and three eutectics (KCl-K3UCl6, K3UCl6-K2UCl5 and K2UCl5-UCl3, respectively). K3UCl6 solid compound exists at relatively narrow temperature range from about 800 K to congruent melting at about 892 K." @default.
- W3179985478 created "2021-07-19" @default.
- W3179985478 creator A5024175680 @default.
- W3179985478 creator A5043958900 @default.
- W3179985478 creator A5076142016 @default.
- W3179985478 date "2021-11-01" @default.
- W3179985478 modified "2023-10-13" @default.
- W3179985478 title "Experimental mixing enthalpy and thermodynamic modelling of UCl3-KCl system" @default.
- W3179985478 cites W1965527483 @default.
- W3179985478 cites W1966893305 @default.
- W3179985478 cites W1988478474 @default.
- W3179985478 cites W2002413355 @default.
- W3179985478 cites W2003159725 @default.
- W3179985478 cites W2027237295 @default.
- W3179985478 cites W2041272247 @default.
- W3179985478 cites W2063671941 @default.
- W3179985478 cites W2076066936 @default.
- W3179985478 cites W2093478891 @default.
- W3179985478 cites W2117911451 @default.
- W3179985478 cites W2167590372 @default.
- W3179985478 cites W2312812303 @default.
- W3179985478 cites W2510147114 @default.
- W3179985478 cites W2564945799 @default.
- W3179985478 cites W2795870452 @default.
- W3179985478 cites W2950342023 @default.
- W3179985478 cites W2951447110 @default.
- W3179985478 cites W2991541122 @default.
- W3179985478 cites W3045737802 @default.
- W3179985478 cites W3129943488 @default.
- W3179985478 cites W4233464572 @default.
- W3179985478 doi "https://doi.org/10.1016/j.molliq.2021.116963" @default.
- W3179985478 hasPublicationYear "2021" @default.
- W3179985478 type Work @default.
- W3179985478 sameAs 3179985478 @default.
- W3179985478 citedByCount "5" @default.
- W3179985478 countsByYear W31799854782021 @default.
- W3179985478 countsByYear W31799854782022 @default.
- W3179985478 countsByYear W31799854782023 @default.
- W3179985478 crossrefType "journal-article" @default.
- W3179985478 hasAuthorship W3179985478A5024175680 @default.
- W3179985478 hasAuthorship W3179985478A5043958900 @default.
- W3179985478 hasAuthorship W3179985478A5076142016 @default.
- W3179985478 hasConcept C113196181 @default.
- W3179985478 hasConcept C121332964 @default.
- W3179985478 hasConcept C138777275 @default.
- W3179985478 hasConcept C147789679 @default.
- W3179985478 hasConcept C178790620 @default.
- W3179985478 hasConcept C18168003 @default.
- W3179985478 hasConcept C185592680 @default.
- W3179985478 hasConcept C190764699 @default.
- W3179985478 hasConcept C2778695967 @default.
- W3179985478 hasConcept C3288061 @default.
- W3179985478 hasConcept C37641323 @default.
- W3179985478 hasConcept C39353612 @default.
- W3179985478 hasConcept C43617362 @default.
- W3179985478 hasConcept C44280652 @default.
- W3179985478 hasConcept C517785266 @default.
- W3179985478 hasConcept C62520636 @default.
- W3179985478 hasConcept C8010536 @default.
- W3179985478 hasConcept C85906118 @default.
- W3179985478 hasConcept C87976508 @default.
- W3179985478 hasConcept C97355855 @default.
- W3179985478 hasConceptScore W3179985478C113196181 @default.
- W3179985478 hasConceptScore W3179985478C121332964 @default.
- W3179985478 hasConceptScore W3179985478C138777275 @default.
- W3179985478 hasConceptScore W3179985478C147789679 @default.
- W3179985478 hasConceptScore W3179985478C178790620 @default.
- W3179985478 hasConceptScore W3179985478C18168003 @default.
- W3179985478 hasConceptScore W3179985478C185592680 @default.
- W3179985478 hasConceptScore W3179985478C190764699 @default.
- W3179985478 hasConceptScore W3179985478C2778695967 @default.
- W3179985478 hasConceptScore W3179985478C3288061 @default.
- W3179985478 hasConceptScore W3179985478C37641323 @default.
- W3179985478 hasConceptScore W3179985478C39353612 @default.
- W3179985478 hasConceptScore W3179985478C43617362 @default.
- W3179985478 hasConceptScore W3179985478C44280652 @default.
- W3179985478 hasConceptScore W3179985478C517785266 @default.
- W3179985478 hasConceptScore W3179985478C62520636 @default.
- W3179985478 hasConceptScore W3179985478C8010536 @default.
- W3179985478 hasConceptScore W3179985478C85906118 @default.
- W3179985478 hasConceptScore W3179985478C87976508 @default.
- W3179985478 hasConceptScore W3179985478C97355855 @default.
- W3179985478 hasLocation W31799854781 @default.
- W3179985478 hasOpenAccess W3179985478 @default.
- W3179985478 hasPrimaryLocation W31799854781 @default.
- W3179985478 hasRelatedWork W1964056987 @default.
- W3179985478 hasRelatedWork W1977102467 @default.
- W3179985478 hasRelatedWork W1998793682 @default.
- W3179985478 hasRelatedWork W2068414341 @default.
- W3179985478 hasRelatedWork W2317140323 @default.
- W3179985478 hasRelatedWork W2376391249 @default.
- W3179985478 hasRelatedWork W2389972902 @default.
- W3179985478 hasRelatedWork W4256532300 @default.
- W3179985478 hasRelatedWork W2399668721 @default.
- W3179985478 hasRelatedWork W3194948265 @default.
- W3179985478 hasVolume "342" @default.
- W3179985478 isParatext "false" @default.
- W3179985478 isRetracted "false" @default.