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- W3180182557 abstract "We report two blue-emitting thermally activated delayed fluorescence (TADF) compounds employing a substituted carbazolophane (Czp) donor (indolo[2.2]paracyclophane). The compounds CNCzpPhTRZ and CF3CzpPhTRZ show emission maxima of 426 nm and 432 nm, respectively, with high photoluminescence quantum yields (PL) of 73% and 80%, respectively. The singlet-triplet energy gap (EST) of both emitters is 0.22 eV, resulting in long-delayed lifetimes of 132 μs for CNCzpPhTRZ and 158 μs for CF3CzpPhTRZ in PPT as the host matrix. Blue organic light-emitting diodes (OLEDs) showed maximum external quantum efficiencies (EQEs) of 7.4% for CNCzpPhTRZ and 11.6% for CF3CzpPhTRZ with electroluminescence maxima of ca. 460 nm." @default.
- W3180182557 created "2021-07-19" @default.
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- W3180182557 date "2021-07-07" @default.
- W3180182557 modified "2023-10-12" @default.
- W3180182557 title "Electron-withdrawing Group Modified Carbazolophane Donors for Deep Blue Thermally Activated Delayed Fluorescence OLEDs" @default.
- W3180182557 doi "https://doi.org/10.33774/chemrxiv-2021-pvx7n" @default.
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