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- W3180527233 abstract "The cascade Michael addition/cyclization reaction of 4-isothiocyanato pyrazolones with ethyl β-benzoylacrylates has been explored by asymmetric organocatalysis, delivering spiro[pyrazolone-pyrrolidinethione] cores bearing three contiguous stereogenic centers in excellent enantioselectivities (up to 95% ee) with excellent yields (up to 91%). This process exhibited broad substrate scope and the advantages of simple operation. A plausible mechanism for this reaction was proposed." @default.
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- W3180527233 date "2021-08-01" @default.
- W3180527233 modified "2023-10-01" @default.
- W3180527233 title "Squaramide-catalyzed asymmetric Michael/cyclization of 4-isothiocyanato pyrazolones and α,β-unsaturated ketones" @default.
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- W3180527233 doi "https://doi.org/10.1016/j.tetlet.2021.153259" @default.
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