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- W3181474662 abstract "This work reports a gold-catalyzed stereoselective synthesis of highly substituted E-configured 2,3-diaza-1,3,5-hexatrienes using α-diazo nitriles and cyclopropene derivatives; such products arise from an atypical diazo attack of α-aryldiazo nitriles at vinylgold carbenes. For these 2,3-diaza-1,3,5-hexatrienes, we develop a novel anionic cyclization of derivatives of one family to form 1H-pyrazolo[4,3-b]pyridine-5-ones." @default.
- W3181474662 created "2021-07-19" @default.
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- W3181474662 date "2021-07-07" @default.
- W3181474662 modified "2023-09-27" @default.
- W3181474662 title "Gold-Catalyzed Synthesis of Diaza-hexatrienes Via Diazo Attack at Vinylgold Carbenes: An Easy Access to 1<i>H</i>-Pyrazolo[4,3-<i>b</i>]pyridine-5-ones" @default.
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- W3181474662 doi "https://doi.org/10.1021/acs.orglett.1c01835" @default.
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