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• W3181569575 abstract "A brand-new self-folding biscavitand was synthesized from a feet-to-feet-connected bisresorcinarene. The X-ray crystal structure of the biscaivtand showed that the two cavities are tightly connected with four butylene linkages. The conformationally coupled two cavities accommodated two cationic guests, showing a homotropic negative cooperativity in nonpolar solvents (toluene and chloroform). A polar tetrahydrofuran solvent weakened the cyclic hydrogen bonding interactions of the biscavitand, which resulted in noncooperative guest binding." @default.
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• W3181569575 date "2021-07-07" @default.
• W3181569575 modified "2023-10-18" @default.
• W3181569575 title "Negative Cooperativity in Guest Binding of a Ditopic Self-Folding Biscavitand" @default.
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• W3181569575 doi "https://doi.org/10.1021/acs.orglett.1c01837" @default.
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