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• W3182069296 endingPage "983" @default.
• W3182069296 startingPage "978" @default.
• W3182069296 abstract "Hexagonally packed coaxial triply helical domains with a mesoscopic length scale in matrices were created from an S1IS2P tetrablock terpolymer/Sh homopolymer blend system, wherein S1, S2, and Sh denote polystyrene, I is polyisoprene, and P represents poly(2-vinylpyridine). Two terpolymers, i.e., S1IS2P-3 (S1/I/S2/P = 0.50/0.17/0.19/0.14, M = 134k) and S1IS2P-4 (S1/I/S2/P = 0.58/0.16/0.10/0.16, M = 173k), were blended with Sh (M = 3k) at various concentrations. In the S1IS2P-3/Sh = 80/20 blend, the helical domain of P (o.d.= 19 nm; h.p. = 34 nm) was displayed by TEM, and the helical I phase (o.d. = 55 nm; i.d. = 29 nm; h.p. = 34 nm) was clearly demonstrated by 3D-TEM tomography. Essentially the same structure was confirmed to be created from the S1IS2P-4/Sh blend. These findings point out that S2 chains fill the gap between the I and P helices, and hence the intermediate S phase also has a helical nature. Moreover, it is worth noting that grains composed of hexagonally packed helices reveal homochirality." @default.
• W3182069296 created "2021-07-19" @default.
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• W3182069296 date "2021-07-09" @default.
• W3182069296 modified "2023-09-26" @default.
• W3182069296 title "Triply Helical Giant Domain with Homochirality in a Terpolymer Blend System" @default.
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• W3182069296 doi "https://doi.org/10.1021/acsmacrolett.1c00307" @default.
• W3182069296 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35549187" @default.
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